ILAR中醇及电解质聚并抑制效应对气液传质的影响研究.pdfVIP

A047 ILAR 中醇及电解质聚并抑制效应对气-液传质的影响 臧晓红 刘延来 王军 （大连理工大学化工学院化学工程系,大连116012） 摘 要 在气升式内环流反应器(ILAR)中加入醇类物质（叔丁醇、季戊四醇、乙醇）及电解质（CaCl2 ）， 考察了聚并现象及其对空气-水体系的气-液传质性能和气含率的影响。结果表明，在水中添加微量醇 类物质会显著增强气-液传质，主要原因为醇类物质抑制了气泡间的聚并行为，但其抑制作用仅发生在 一定的浓度范围内，超过极限浓度后只能形成泡沫，不能改变气泡平均表面平衡直径，对增强传质无 益；叔丁醇和季戊四醇的碳链尽管长于乙醇，但气泡聚并抑制效果不及乙醇，分析可知，空间结构对 醇系列的聚并抑制效果有一定的影响。向水中添加电解质后，氧的体积传质系数增加显著，本文从离 子强度的角度对电解质抑制气泡聚并进行了分析。 关键词 气泡聚并 气含率 表面活性物质 中图分类号 X792.031 文献标识码 A THE EFFECT OF COALESCENCE SUPPRESSION BEHAVIOUR OF THE LIQUID ON GAS-LIQUID MASS TRANSFER IN AN INTERNAL LOOP AIRLIFT REACTOR ZANG Xiaohong , LIU Yanlai , WANG Jun (Department of Chemical Engineering, Dalian University of Technology, Dalian 116012 , China) Abstract An experimental study has been aimed at examining the coalescence phenomena in aqueous solutions of alcohols (tertiary butanol, pentaerythritol, ethanol) and electrolyte (CaCl2) and at determining the effect of these surface-active compounds on gas-liquid mass transfer and gas hold-up in an internal airlift loop reactor. The experimental results show that the addition of alcohols into the water will increase the gas-liquid mass transfer coefficient of oxygen and gas hold-up significantly because the alcohol solutes change the coalescence 联系人: 王军，副教授. E-mail: wjun@ dlut.edu.cn 第一作者: 臧晓红, 女, 硕士研究生. 基金项目: 国家自然科学资助项目（No ） behavior of aqueous solutions drastically. The inhibition of coalescence, however, occurs in a narrow concentration range. Beyond a limiting concentration, further addition of alcohols only causes the formation of undesirable foams and does not change average surface equivalent diameters. Comparison of mass transfer data among the alcohols reveals that although the lengths of carbon chain of tertia