丙烷脱氢制丙烯催化剂烧焦过程的模型化研究.pdfVIP

2008 年中国过程系统工程年会会议论文集 丙烷脱氢制丙烯催化剂烧焦过程的模型化 张新平，周兴贵，袁渭康， （华东理工大学化学工程联合国家重点实验室，上海 200237 ） 摘要：丙烷脱氢制丙烯在反应的过程中，由于焦的沉积使催化剂活性不断降低，而且失活速度很快，催化剂需频繁烧焦 再生。本文在研究了丙烷脱氢催化剂烧焦过程内外扩散影响的基础上，采用内扩散效率因子修正的均匀烧焦物理模型， 建立了综合考虑内外扩散影响的绝热固定床非均相动态烧焦数学模型，可用于指导反应器的设计和操作优化。通过对 Cr O /Al O 脱氢催化剂烧焦过程模拟，能对烧焦过程的变化规律提供更深入的认识。 2 3 2 3 关键词：丙烷脱氢；烧焦；催化剂再生；非均相；数学模型 中图分类号：TQ051.14 文献标识码：A 文章编号： Modeling of coke burning-off regeneration for coked propane dehydrogenation catalyst ZHANG xin-ping, ZHOU xing-gui, YUAN wei-kang （State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China ） Abstract ：In propane dehydrogenation to propene, the catalyst is continuously deactivating owing to coke formation, which needs to be burnt off periodically to regenerate the catalyst. In this paper, an effectiveness factor modified coke burning-off model was used and a dynamic heterogeneous model for the reactor was established, which takes into consideration the pore and film diffusion effects. Simulation study show that there is a large temperature difference between gas and solid. At the beginning of coke burning-off, because the accumulation of the reaction heat, the temperature of solid increases rapidly, which is more obvious near the inlet of the reactor. it quickly drops to the same temperature with gas when the carbon burning is close to completion. Coke burning-off gradually advancing along the bed, hot temperature of bed also gradually advancing from the inlet to outlet. In a different bed position, the hot temperature was similar. Key words ：propane dehydrogenation; coke burning-off; catalyst regeneration; heteroge