磁性Fe3O4膨胀石墨对亚甲基蓝的吸附性能研究.doc

磁性Fe304/膨胀石墨对亚甲基蓝的吸附 性能研究 范文娟常会 攀枝花学院生物与化学工程学院 以膨胀石墨(EG)为载体，采用简单的水热法，制备出磁性Fe3O,/膨胀石墨 (MEG) o采用X-射线衍射仪(XRD)和扫描电子显微镜(SEM)对MEG的组成结 构和形貌进行表征。以亚甲基蓝为H标污染物，探讨了溶液pH值、吸附时间、 盐离子浓度和亚甲基蓝初始浓度对吸附性能的影响，并对吸附动力学和吸附等 温线进行研究。结果表明：当亚甲基蓝初始浓度为50 mg* L pH值为7，吸附 时间为60 min时,对亚甲基蓝的去除率和吸附量分别为97. 03%和48. 52 mg ? g 随着溶液中盐离子Na和Ca2+浓度的增加，MEG对亚甲基蓝的吸附性能降低;MEG 对亚甲基蓝的吸附行为符合拟二级动力学模型和Langmuir等温吸附模型。MEG 可以使用磁铁进行分离回收，回收率达95. 71%。5次吸附-再生后，吸附量仍较 高为41. 72呵? g说明MEG吸附剂具有较稳定的重复使用能力。 关键词： 磁性k304/膨胀石墨;亚甲基蓝;吸附;磁分离; 范文娟(1983-),女，四川省人，，讲师。 基金：四川省细鱗片深加工重点实验室项S (2013004-2014) Study on the Adsorption Property of Magnetic Fe304/Expanded Graphite for Methylene Blue FAN Wen-iuan CHANG Hui College of Biology Chemical Engineering， Panzhihua University: Abstract： Using expanded graphite ( EG) as carrier， the magnetic Fe3O4/expanded graphite ( MEG) was prepared by hydrothermal method. The structures and morphologies of the MEG were characterized by Xray diffraction ( XRD) and Scanning electron microscope ( SEM) . Methylene Blue was used as a probe pollutant to investigate the effects of pH value, adsorption time, salt ionic strength and initial concentration on adsorption property, corresponding adsorption kinetics and adsorption isotherm were researched. The results indicate that the adsorption rate and adsorption capacity of 50 mg ? L_l methylene blue can reache 97. 03% and 48. 52 mg ? g1 in the condition of pH 7，absorption time 60 min; The adsorption capacity reduces with the Na* and Ca2+ increase; the adsorption behavior is mainly in accordance with the pseudo-second-order kinetics model and Langmuir model. The recovery rate can reach 97. 51% by magnet. The adsorption amount for Methylene Blue is also 41. 72 mg ? g1 after five adsorption-regeneration cycles， which show that MEG has stable reuse ability. Keyword： magnetic Fe304/expanded graphite; methylene Blue; adsorption; magnetic separation; 1引言 随着染料工业的迅速发展，染料废水的排放量巨大，占工业废水排放总量的 35%左右。染料废水中含冇大量苯基、偶氮基和氨基等致癌性冇机物，因其成分 复杂且稳定、有机污染物含量高，难生化降解、水质变化大等特点［1-3］，如不 经过处理直接排入水中会造成水体