[工学]4 Molecular weight and sizes.pdf

Polymer Physics Polymer Physics Polymer Physics 高分子物理 高分子物理 高分子物理 4 Molecular weights 4 Molecular weights and Sizes and Sizes 高分子的分子量与尺寸 4.1 Molecular weights and molecular weight distribution 分子量与分子量分布 Characteristics of polymer molecular weights 高分子的分子量的特点 The molecular weights are very high, ranging from about 25,000 to 1,000,000 g/mol or higher. The molecular weight of ordinary size molecules is fixed (e.g., benzene has a molecular weight of 78 g/mol regardless of its source). Most polymer molecular weights, on the other hand, vary greatly depending on the method of preparation. In addition, most polymers are polydisperse; that is, the sample contains more than one species. Molecular weight averages 平均分子量 Number-average molecular weight ∑ N M ∑ w M i i i i i n ∑i N i ∑i (wi / M i ) Weight-average molecular weight ∑ N M 2 ∑ w M M i i i i i i w ∑N M ∑w i i i Z-average molecular weight ∑ N M 3 ∑ w M 2 M i i i i i i z ∑N M 2 ∑w M i i i i Viscosity-average molecular weight 1/ a +a ∑ N M 1  M v  i i i  Schematic