Revealing the chemistry of biomass pyrolysis by means of…通过揭示生物质热解的化学过程.pdfVIP

Electronic Supplementary Material (ESI) for RSC Advances This journal is © The Royal Society of Chemistry 2013 Revealing the chemistry of biomass pyrolysis by means of tunable synchrotron photoionisation - mass spectrometry a b b b a a c a A. Dufour *, J.J. Weng , L.Y. Jia , X.F. Tang , B. Sirjean , R. Fournet , N. Brosse , F. Billaud , G. Mauviela 2 , F. Qi * a Reactions and Processes Engineering Laboratory, CNRS, Lorraine University, ENSIC, 1 rue Grandville, B.P.20451, 54000 Nancy Cedex, France. anthony.dufour@ensic.inpl-nancy.fr b National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China,fqi@ustc.edu.cn c LERMAB, Lorraine University, B.P.239, 54506 Vandoeuvre les Nancy Cedex, France. Supplementary material ___________ 1. Mass spectra Figure S.1. Mass spectrum of volatile products from miscanthus pyrolysis with photon energy set at 9.5eV and pyrolysis reactor at 350°C Figure S.2. Mass spectrum of volatile products from the pyrolysis of xylan (birch, Sigma Aldrich) with photon energy set at 9.5eV and pyrolysis reactor at 350°C Electronic Supplementary Material (ESI) for RSC Advances This journal is © The Royal Society of Chemistry 2013 Deeper works are needed to solve the chemical structures of the major species produced from xylan pyrolysis from m/z 124 (124, 136, 138, 152, 162, 164, 178, 192, 206). To the best of our knowledge, these species have never been reported from MBMS with higher ionisation energy [4a,d,21,22b] or from Pyrolysis-GC/MS [19,20]. These highly reactive species (rich in oxygen) are detected here probably than