Synthesis of PbTe based thermoelectric materials PbTe-材料合成化学课件PPT.pptVIP

Introduction of Thermoelectric materials PbSeTe/PbTe QDSLs Synthesized with MBE PbTe nanocomposites synthesized from PbTe nanocrystals seebeck heat electricity peltier thermo electric power generation refrigeration Thin-film material PbSe1-xTex/PbTe Bulk material PbTe based nanocomposite AgPbmSbTe2+m ZT 0.9 at 300 K 2.0 at 550 K ZT 2.1 at 800 K nude Bayard-Alpert gauge RHEED system The effusion cells contain PbTe, PbSe, Te, Bi2Te3 substrate BaF2 Pb(CH3COO)2·3H2O PbTe nanocrystals PbTe bulk material Solvothermal route spark plasma sintering (SPS) Te Mixture Pb(CH3COO)2·3H2O Te Solvent : en and DMF Alkaline solution-- NaOH Reductant --NaBH4 . reaction In a sealed 500 ml autoclave with solvent filling 80% of the capacity heated with stirring Cooled to room temperature gray powders were collected, cleaned distilled water, ethanol and acetone dried in air a pulsed dc current conducts through both the graphite die and the specimen under high pressure. This heats the specimen internally, providing uniform and rapid thermal ramping while minimizing the sintering time and temperature, thus effectively limit grain growth. FIG. 1. SEM micrograph of PbTe fracture surface indicating 100 nm to over 1 μm grains distributed within a bulk material.