The Spark Plasma Sintering Process-材料合成化学课件PPT.ppt

Ceramic obtained by SPS with a larger grain size of about 2 μm. Nevertheless, this value is still significantly lower than the one observed in a ceramic obtained from this precursor by conventional sintering (about 10μm). The Spark Plasma Sintering Process Typical classification for powder sintering processing What’s SPS SPS ― Spark Plasma Sintering Advantage: The wide range of materials available high-speed processing low sintering temperature Energy saving What Can the SPS Process Do? The Basic SPS Configuration Mechanism of the SPS Process Spark plasma Joule heat Pressure Mechanism of the SPS Process Material transfer path during sintering Mechanism of the SPS Process Several Interesting Examples Diamond formation from carbon nanotubes at very low pressure by spark plasma sintering Experiment condition The starting material Apparatus axial pressure and temperature 80 MPa and 1500℃ Dr Sinter? model SPS-1050 spark plasma sintering system multi-walled carbon nanotubes (MWCNTs) produced by catalytic chemical vapor deposition (CCVD) The heating rate 100 K/min The DC pulses Current:1000 A, voltage:5 V a pulse duration of 12 ms and a pulse interval of 2 ms High-resolution TEM image of the starting multiwall carbon nanotubes the MWCNTs are 20–50 nm in diameter and up to several tens of micrometers in length, with closed tips. SEM images of the sintered nanotube compacts at 1500 ℃and only 80 MPa during SPS single diamond crystals (a), a large, single diamond crystal (b), An agglomerated diamond crystal (c), and a large agglomerated diamond crystal (d). The transformation model of carbon nanotubes to diamond in SPS BaTiO3 ceramics prepared by SPS conventionally sintered at 1400℃ for 2 h SPS(Ph= 50 MPa, Ti=1200 ℃, Pi =100 MPa, ti=5 min ) Optical micrographs of the polished surfaces of BaTiO3 ceramics Preparing Ultrafine Nanocrystalline Bulk Material of Pure Rare-Earth Metals Gd  Figure 1. Schematic diagram of preparing the