TiO2 and H2Ti3O7 xH2O nanotubes synthesized by hydrothermal method-材料合成化学课件PPT.ppt

TiO2 and H2Ti3O7·xH2O nanotubes synthesized by hydrothermal method Timeline References of hydrothermal method Formation of titanium oxide nanotube, Langmuir,1998 Titania nanotubes prepared by chemical processing, Adv. Mater.,1999 H2Ti3O7-typed nanotubes made vis a single alkaline treatment, Adv. Mater.,2002 Formation,structure,and stability of H2Ti3O7·0.8H2O nanotubes, J.Phys.Chem.B., 2005 Protonated titanates and TiO2 nanostructured materials：synthesis,properties,applications, Adv. Mater., 2006 Composition after chemical treatment 1.Si ≈0.7mol% , by ICP-AES. 2.Na+ ≈0.15%, by AAS. 3.Ti and O , by energy-dispersive X-ray (EDX). Specific Area (SA) 1.SA of the as-precipitated was 150m2 g-1. 2.SA ≈400m2 g-1 after treatment at 100℃ with 10M NaOH TEM and Selected-area electron diffraction Conclusion To discuss the effect of SiO2 doping, commercial TiO2 (mixture phase of rutile and anatase) was also treated, the tube-shaped products were also found. Mechanism of the formation of the nanotube is not clear and is under investigation. Oxide nanotubes can be obtained easily via chemical treatment. TEM Laser Raman Spectra TG-MS and SEM Hypothesis Synthesis of H2Ti3O7 nanotube experiments raw material：anatase TiO2, TiO2 made by Sol- gel, amorphous TiO2 . reaction time with NaOH：12、24、48 and 72h . Treatment with NaOH：NaCl、NaNO3、 　　　 LiOH(nanoparticle)、KOH(nanorod) . Washing with water：ethanol、acetone . Treatment with HCl：with and without . characterization--EDX、EESL、IRS Both EDX and EESL spectra show merely Ti and O, only when the examination area was increased to co- ver some non-tubular particles, Na was detected. Infrared spectroscopy of the specimen indicates that OH bonds constantly exist in the nanotubes, implying that the nanotubes might be the