苯乙烯形状记忆聚合物的制备及性能分析-工程力学专业论文 word格式.docx

AbstractShapememorypolymer(SMP),anewtypeofsmartmaterials,haslotof advantages,suchaslargereversibledeformation,easymolding,adjustabledeformationtemperatureandlowcostofproduction.However,thermallyinduced SMPtypicallyneedaforceintheprocessofpre-deformation,anditsresponseneed hotmediumtodrivetheinitialshape.Thelowdrivingefficiencyanddifficultimplementationlimititsapplications.Inthisthesis,aseriesofstyreneSMPweresynthesizedbyfreeradicalcopolymerization,whichwasdrivedbyinfraredlaserandmagnetic-heat.Firstly, copolymerization wasemployedtoprepareaseriesofstyreneSMP throughthecomonomercontentandcrosslinkercontrol.ThesynthesizedstyreneSMPshowedgoodmechanicalpropertiesandexcellentshapememoryperformances.Whenthedrivedtemperaturewasequaltoorhigherthantheglasstransition temperature(Tg),theshaperecoveryrateofthestyreneSMPwasgreaterthan95%, andtheshaperecoveryspeedwasquickly.ThisstyreneSMPwasanamorphous polymeranditschemicalstructureswasstable.IthadanadjustableTgfrom60oCto95oC,andhighthermal decompositiontemperature.Inaddition, rubberelastictheorywasusedtoanalyzetheentropychangeintheprocessofshaperecovery.Itdemonstratedthattheshapememoryeffectwasduetotheentropyincrease.Basedon thetheoryofthermodynamicsandentropyelasticitytheory,therelationshipsbetweenentropychangeandcross-linkingdensityofnetworkwerestructured qualitatively.Resultsshowed that,withthecrosslinkingdensityofnetworkincreased,theshaperecoverytrendwassignificantlyandshapememoryeffectwasmoreobvious.Secondly,theγ-rayradiationresistantcapabilitywasstudied.Thesynthesized styreneSMPshowedbetterthermalproperties,dynamicmechanicalpropertiesandthermalstabilityatadoseof1×105Gyofγ-rayradiation.Whentheradiationdose increasedto1×106Gy,thecrosslinkdensitybecamelower,whilethedynamicmechanicalproperties,glasstransitiontemperature,staticmechanicalpropertiesandshape memory behavior did not have significantly changes. However, when theirradiationdoseoftheTgammaraywasincreasedtoT65×10Gy,theglasstransition6temperature,thermalstabilityanddynam