锂离子电池硅负极的失效行为与性能改进-化学工程与技术专业论文.docx

Classified Index: TM912.9 U.D.C.: 621.355Dissertation for the Doctoral Degree in EngineeringFADING BEHAVIOR AND PERFORMANCE IMPROVEMENT OF SILICON ANODE FOR LITHIUM ION BATTERIESCandidate:Xu YuhongSupervisor:Yin GepingAcademic Degree Applied for:Doctor of EngineeringSpecialty:Chemical Engineering and TechnologyAffiliation:School of Chemical Engineering and TechnologyDate of Defence:June, 2010Degree-Conferring-Institution:Harbin Institute of Technology摘要高容量负极材料已经成为锂离子电池发展的目标之一，而硅材料因具有高 达 4200mAh·g-1 的理论比容量而成为研究热点之一。但是硅负极材料在电化学 循环过程中存在较大的体积变化，从而造成了电化学循环性能的迅速恶化。因 此，有效抑制硅的体积变化造成的结构破坏、提高其电化学循环性能是本领