聚乳酸环氧基笼型倍半硅氧烷纳米复合材料的制备与性能分析-材料学专业论文.docx

关键词：聚乳酸，环氧基笼型倍半硅氧烷，纳米复合材料，力学性能，流变行为，结晶动力学。Investigation of the Preparation and Properties of Poly (lactic acid) / Epoxy Polyhedral Oligomeric Silsesquioxanes NanocompositesABSTRACTPoly(lactic acid) (PLA) is one of the most widely used biobased-plastics which are the most mature of industrialization. However, the further appliacations of PLA have been restricted by its weaknesses. Epoxidized polyhedral oligomeric silsesquioxanes (EVOS) posses reactive epoxy groups and thermal stability, it might be used as functional filler to improve the overall mechanical properties of PLA .The PLA/EVOS composites prepared in an internal mixer via melt blending, and the mechanical properties, rheological properties and crystallization kinetics of the composites were characterized in terms of infrared spectrometer, scanning electron microscopy, dynamic mechanical thermal analyzer, tensile testing machine, capillary rheometer and DSC.The results of mechanical properties revealed that the impact strength at 5 wt% EVOS loading, the tensile strength at 1 wt% EVOS loading and the elongation at break at 0.5 wt% EVOS loading were increased by 22.8%, 8.3% and 68.9% compared to pure PLA, respectively. The DMA results showed that the storage modulus of PLA/EVOS nanocomposites increased initially and then decreased with the increase of the EVOS content, the maximal storage modulus was obtained in the case of 0.5 wt %, increased by 49% versus pure PLA. The SEM images reflected that the incoration of EVOS can initiate the formation of massive crazes, which absorbed more impact energy under external force and thus improved the toughness of PLA.PLA/EVOS nanocomposites is pseudoplastic fluid, non Newtonian index increased with the increasing temperature; and non Newtonian index tended to increase and then decrease with the increase of the EVOS content.The values of avrami index for pure PLA and its nanocomposites were in the range or2.15~2.62 and 2.24~2.66, respectively. It is inferring that the nu