配位修饰铟硫属化合物合成-无机化学专业论文.docx

Syntheses of Coordination Modified Indium Chalcogenide CompoundsAbstractOrganic-inorganic hybrid materials are one of the most active research fields in materials science in recent years. Organic hybrid chalcogenide materials have been attracted considerable interests not only due to their novel structures but also due to their unique physical and chemical properties, such as catalysis, adsorption, ion exchange, photoluminescence, nonlinear optics and semiconductor. The syntheses of these materials are typically carried out under hydro(solvo)thermal conditions using structure directing agent (or template) of the organic amines or quaternary ammonium salts. Tetrahedral ortho-anions MQ4 (M = Ga, In, Sn, Sb; Q = S, Se, Te) or pyramid anions MQ3 (M = Sb; Q = S, Se) as primary building units exhibit a characteristic tendency to condense through corner- or edge-sharing to afford a variety of structures of the chalcogenidometalate anions. In the research of main group chalcogenides, design and synthesis of open-framework structure and nano clusters is the frontier and trend in current research, in which the metal sulfides modified with transition metal coordination moieties have been the focus of research. The nanometer supertetrahedral clusters and wheel-like clusters with the novel structure types and sizes are becoming a new research direction to the development of nanostructured materials. In the synthetic methods for main group chalcogenides, selecting new amine system and using ionic liquid medium are very important to prepare new organic-inorganic hybrid materials. The research goal of this work is the synthesis of indium chalcogenide clusters or compounds modified by coordination complexes. Supertetrahedral cluster compounds with novel linkages and wheel-shaped indium chalcogenide clusters were synthesized by selecting 1, 2-diaminocyclohexane (dach) as the reaction solvent and chelating agent. The synthesis conditions, influence factors, such as using or without us