er yb共掺铌镁酸铅审审钛酸铅陶瓷电学及上转换发光性质的研究word格式论文.docx

优秀毕业论文 精品参考文献资料 在不同极化电场下，对 PMN-PT: Er3+/Yb3+陶瓷样品进行极化后，研究极化 场强对 Er3+/Yb3+共掺 PMN-PT 陶瓷样品压电性能和上转换荧光强度的影响。发 现样品在经过极化处理后，会改变上转换荧光的强度，对其荧光峰位没有影响， 这样可以把上转换荧光光谱作为定标，表征材料的极化状态。 关键词：Er3+/Yb3+；PMN-PT；极化；上转换发光  Abstract Because Pb(Mg1/3Nb2/3)O3 ceramics possess the excellent electrical properties. The PMN-PT ceramics is the binary system of Pb(Mg1/3Nb2/3)O3 with PbTiO3, whose piezoelectric constant d33 reach 500pC/N and dielectric constant is 20000 in the Morphotropic Phase Boundary. Besides, its electromechanical coupling coefficient is high. Because of the good property in piezoelectric, ferroelectric and dielectric, it is the appropriate material for the high-power piezoelectric ceramic transformer. The Energy level of Er3+ is much more than the other rare earth ions, which is evenly distributed, so it is beneficial to the upconversion photonluminescene. Besides, The Yb3+ is the most important sensitizer to improve the efficiency of upconversion. When Er3+/Yb3+ co-doped in the material, whose light-emitting efficiency is higher than the separate Er3+. In addition, the upconversion is correlated with material. When the phonon energy is lower, the efficiency of upcongversion is better. The PMN-PT ceramics is a goog matrix for the upconversion. Up to now, the relationship between the upconversion and the effect of poling is never reported, so it will be a major approach to the thesis. Firstly, the PMN-PT ceramics and Er3+/Yb3+ co-doped PMN-PT ceramics is prepared by solid-state reaction with different sintering temperature. The sample must be pure calcium perovskite structure and the compactness reach more than 70%. Trough the Scanning Electron Microscopy, the grain size of sample is observed. Then the ceramic is silver after polishing, we will test the ferroelectric, piezoelectric and dielectric properties. To find the best sintering temperature be 1200℃, the sample, which is sintered by this temperature, is the best ceramic. Compare between the PMN-PT: E