无机材料制备与合成.pptVIP

Logo Logo A Simple Route to Alloyed Quaternary Nanocrystals Ag-In-Zn-S with Shape and Size Control Applied Chemistry : Wang Guoguang Contents 1 2 3 4 INTRODUCTION EXPERIMENTAL SECTION RESULTS AND DISCUSSION CONCLUSIONS INTRODUCTION binary semiconductor nanocrystals biomedical fluorophores light-emitting diodes (LEDs) photovoltaic cells (PC) disadvantage: binary compounds showing desired spectroscopic properties frequently contain toxic elements such as Cd,Pb, or Hg ternary semiconductor nanocrystals heavy metals-free appropriate band-gap energies direct band-gap semiconductors alloyed quaternary nanocrystals band gaps covering almost the whole visible spectrum as well as a part of the near-infrared high photoluminescence quantum yields band gaps could be tuned Aim: ①We report the synthesis of quaternary Ag-In-Zn-S nanocrystals with different shapes, sizes, and compositions using the simple and commercially available chemicals silver nitrate, indium(III) chloride, zinc stearate, and DDT as precursors and ODE as solvent. ②The off-stoichiometry effects on crystal structure and optical properties of the quaternary Ag-In-Zn-S system were also observed and discussed. EXPERIMENTAL SECTION Materials： silver nitrate (99%) indium(III) chloride (98%) zinc stearate (technical grade) 1-dodecanethiol (DDT, 98%) sulfur (99%) 1-octadecene (ODE, 90%) oleylamine (OA, 70%) Sigma-Aldrich Preparation of Ag-In-Zn-S Nanocrystals Silver nitrate (0.03 g, 0.17 mmol), indium(III) chloride(0.132 g, 0.59 mmol), zinc stearate (0.63 g, 1.0 mmol), and DDT (0.4g, 0.98 mmol) were mixed with ODE (15 mL) in a three-neck flask. The mixture was heated under argon flow to 150 °C until a homogeneous solution was formed. Then sulfur (15 mg, 0.47 mmol) dissolved in 1 mL of OA was quickly injected into the reaction solution. The temperature was raised to 180°C, and the mixture was kept at this temperature for 60 min.