激光诱导击穿光谱中的等离子体发射光谱增强方法分析-analysis of plasma emission spectrum enhancement method in laser induced breakdown spectroscopy.docx

华中科技大学博士学位论文 华 中 科 技 大 学 博 士 学 位 论 文 II II 附近的观点。通过对铝等离子体冷凝后的颗粒再次加热激发后不仅成功改进了 Al 原 子光谱谱线的分辨率，还改进了 Al 原子谱线线宽，同时，抑制了 Al 原子光谱谱线的 自吸收效应。 （4）首次提出将空间约束与双脉冲 LIBS 相结合的增强方案，并成功将平行面板 应用于双脉冲激发的 LIBS 中，在调整平行面板距离后接着调整两激光脉冲之间的时 间间隔，从而获得平行面板空间约束条件下，双脉冲 LIBS 的最佳增强效果。最佳的 增强效果可以达到 168.6 倍。 本论文所研究开发的半球形空间约束，磁-空双重约束以及空间约束与双脉冲 LIBS 相结合的混合增强技术对激光等离子体的光谱增强效果显著，设计制作简单， 成本低，具有十分广阔的发展空间和应用前景。同时也为提高 LIBS 探测灵敏度提供 了一系列全新的研究方法。 关键词： 激光诱导击穿光谱 等离子体 激光诱导等离子体光谱 磁约束 空间约束 原子光谱 III III Abstract Laser-induced breakdown spectroscopy (LIBS), which uses focusing a powerful pulsed laser beam onto a sample to create a plasma, by spectrally analyzing the optical emission from the plasma, the element composition and content of the sample could be deduced. The significant attributes of LIBS technique are: ability to detect all elements, simultaneous multi-element detection capability, no need to vacuum, little or no sample preparation, non-destructive to the sample, real-time analysis, in situ diagnosis and remote detection. Therefore, since it was appeared, LIBS technique has been drew widespread attention, and it is developing to one of a valuable spectral analysis technique. Now, successful applications of LIBS has been found in many areas, such as chemical and biological hazards analysis, geological survey, artwork detection and space exploration. However, the poor limit of detection, low precision of analysis, lead to the low detection sensitivity of LIBS, has become the bottleneck of its further development, how to improve the LIBS detection sensitivity, which has become an important research subject in future. The main study of this thesis is using new-style space confinement, magnetic field and space confinement combination, dual-pulse excitation, and dual-pulse excitation and space confinement combination to further improve the optics emission intensity and accuracy of analysis from laser-induced plasma. After lot of research work, the following achievements and points of innovation: The spatial confin