gral审审mg复合材料抗热震与抗烧蚀性能研究-study on thermal shock resistance and ablation resistance of mg composite by gral examination.docxVIP

AbstractInthethesis,thetranspirationcoolantweredeterminedaccordingtothematerialdesign.Gr/Al、Gr/75Al-25Mg、Gr/50Al-50Mg、Gr/25Al-75MgandGr/Mgwerepreparedbymeanofsqueezecastingtechnology.Byusingopticalmicroscope,scanningelectronmicroscope(SEM),dilatometer,thermalconductivitytester,three-pointbendingtests,themicrostructure,mechanicalandthermophysicalpropertieswereexaminedandtheirinfluencingfactorswerediscussed.ThemicrostructureafterablationwereinvestigatedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Mechanismsofthermalshockandablationresistanceofthecompositeshadalsobeenstudied.Compositeswhichchosenpuremetalascoolanthavehighestbendingstressandthermalconductivity,anditdroppedwithmixingscalesofmetalcoolant.TheelasticmodulusandmeanCTEs(20℃～100℃)ofcompositesbothdeclinedwiththeincreasesofvolumeMgincoolant.AccordingtoGJB323A-96,weconductedoxygen-ethanetorchheatingtest.Theresultsshowedthatcompositedoesnotburstapartwhenthematerialisinstantlyheatedandwhentheablationisjustover.Itsthermalshockresistanceisgood.ThetransienttemperaturefieldandthermalstressfieldsaffectedbyheattransferinhightemperatureweresimulatedandanalyzedbasedonthethermalphysicaldatawithANSYScommercialsoftware.Theresultrevealthatinthefirst10s,temperaturechangessharply,thermalstressreachedmaximumat2s;after15stemperaturefieldsgraduallybecamestable,thermalstressfieldsdroppedwithit.ThermalstressfieldswerehighestinGr/50Al-50Mg,andithavelowstrength;Thermalstressfieldswerelowestandstrengthwerehighincompositeswhosetranspirationcoolantispuremetal.Sothethermalshockresistanceofpuremetalimpregnatedgraphitewasbest.ThesurfaceofthesamplesafterablationwerecoatedbyAl2O3,MgOortheirmixer.Coolantpresentedobviouslyagradualdistributioninthecrosssection.Themasslossratioofcompositeswereintherangeof6.6×10-4～71.8×10-4g/s,whichshowedgoodablationresistanceproperties.Themasslossratioofcompositesdecreasedwithprolongingofablationtimeandincreasinginmixingscalesofmetalcoolant.Theablationresistancefor30sofGr/50Al-50Mgwasbestinthefivecomp