镧钴取代m型永磁铁氧体磁性能分析-analysis of magnetic properties of lanthanum cobalt substituted m - type permanent magnet ferrite.docxVIP

ABSTRACTSince the M type permanent ferrite MFe12O19 (M = Ba, Sr, Pb) was found in the 1950s, it has been widely used in various fields due toits advantages such as low-cost, large output andhardly oxidized. In spite of their relatively modest magnetic properties, the ferrite magnets still show the best performance to cost ratio. For that reason, and despite the recent development of the rare earth based magnets, hard ferrites still remain the first permanent magnet material both in tonnage and in value.To fulfill the market requirements, ferrite magnets with improved magnetic properties have always been developed.The latest breakthrough is based on partial substitutionswith rare earth elements, preferably lanthanum, and withtransition metals, preferably cobalt, using a Sr1-xLaxFe2n-yCoyO19 modified chemical formula.This paper studies the M-type lanthanum cobalt substitutedpermanent ferriteSr1-xLaxFe2n-yCoyO19, which wasprepared by the traditional ceramic process. The influence of lanthanum-cobaltsubstitution, calcium-silicon doping and other factors onthe microstructure and magnetic properties of M type permanent ferrite Sr1-xLaxFe2n-yCoyO19 was carefully investigated. Lanthanum cobalt substituted M type permanent magnetic strontium ferrite Sr1-xLaxFe2n-yCoyO19 was investigated bydesign of experiment methods, mainly because of the DOE method is easy to program and analysis, especially in determining the key factors from many related factors, and tell the interactions between the factors.First of all, in this paper, doping amount of lanthanum cobalt before pre-sintered, pre-sintering temperature and secondary lanthanum cobalt doping amount, sintering temperature were analysed as the research object. By means of Pareto diagram the key factors and the interaction between factors are investagated. Then the doping amount of lanthanum, cobalt, silicon, calcium were analysed to mainly research aboutthe influence ofSiCa oxide and its combination on microstructure an