锂离子电池正极材料li3v2po43c的制备及改性研究-preparation and modification of li 3 v2 po 43 c cathode material for lithium ion batteries.docxVIP

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锂离子电池正极材料li3v2po43c的制备及改性研究-preparation and modification of li 3 v2 po 43 c cathode material for lithium ion batteries.docx

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锂离子电池正极材料li3v2po43c的制备及改性研究-preparation and modification of li 3 v2 po 43 c cathode material for lithium ion batteries

ABSTRACTLithiumionbatterycathodematerialLi3V2(PO4)3/Cwassynthesizedbyanimprovedsol-gelmethod.Citricacidisusedascarbonsourceandcomplexingagent.ThesamplewithoptimumelectrochemicalperformancecanbeobtainedbyadjustingthepHvalueinthesol-gelprocess.Zn-dopedLi3V2-xZnx(PO4)3/C(x=0,0.01,0.02,0.03)cathodematerialsweresynthesizedalsobytheimprovedsol-gelmethod.ThecompositionandmicrostructureofthesecompositeswereevaluatedbyXRD,SEMandHRTEM.ThecathodefilmsweremadebyLi3V2-xZnx(PO4)3/C(x=0,0.01,0.02,0.03)powderandthenassembledintolithiumbatteries.Theelectrochemicalperformanceswerecharacterizedbycharge/dischargetest,electrochemicalimpedancespectroscopy,cyclicvoltammetryandpotentialstepchronoamperometry.TheelectrochemicalperformancesofLi3V2(PO4)3/CcathodematerialspreparedunderdifferentpHvalueswereevaluated.Theresultsofgalvanostaticcharge-dischargeindicatedthatthesamplepreparedatpHvalueof4exhibitsanoptimumcapabilityatlow-rate.ThesamplepreparedatpHvalueof9possessesagoodperformanceathigh-rate.At1C,forexample,theinitialdischargecapacityofsamplespreparedatpHvalueof4and9was131.7and125.8mAhg-1,respectively,whiletheinitialdischargecapacityofsamplespreparedbytraditionalsol-gelmethodwas73.9mAhg-1.At5C,theinitialdischargecapacityofsamplespreparedatpHvalueof4and9was75.2and98.5mAhg-1,respectively,whiletheinitialdischargecapacityofsamplespreparedbytraditionalsol-gelmethodwas50.6mAhg-1.Zn-dopedLi3V2-xZnx(PO4)3/C(x=0,0.01,0.02,0.03)cathodematerialsweresynthesizedbyanimprovedsol-gelmethodpHvaluewascontrolledat4duringtheprocess.ItwasfoundthatZn-dopedsampleswereperformedwellathighrate.TheLi3V1.97Zn0.03(PO4)3sampleexhibitedthebestelectrochemicalperformanceathighrates.Forinstance,thesampleshowedhigherinitialdischargecapacityof131.5and100.7mAhg-1thanthoseofunmodifiedsample(73.9and50.6mAhg-1)at1Cand5C,respectively.KEYWORDS：Lithiumionbattery;Cathodematerial;Li3V2(PO4)3;Zn-dopedmodification;Electrochemicalperformanceii目录第一章文献综述....................................................................................