利用生物质基合成气制备清洁生物燃料的分析-analysis of using biomass-based syngas to prepare clean biofuel.docxVIP

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利用生物质基合成气制备清洁生物燃料的分析-analysis of using biomass-based syngas to prepare clean biofuel.docx

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利用生物质基合成气制备清洁生物燃料的分析-analysis of using biomass-based syngas to prepare clean biofuel

ABSTRACTA mixture oxide catalyst of Fe1.5Cu1Zn1Al1K0.117 was successfully applied for high efficient production of the clean biofuels from two different bio-syngases derived the biomass gasification and the bio-oil reforming (defined as BGS and BRS). The maximum biofuels yield using BGS reached about 1.59 kg fuels/(kgcat h) with a contribution of 0.57 kg alcohols/(kgcat h) and liquid hydrocarbons (LHC) of1.02 kg LHC/(kgcat h), which is very close to the methanol yield 1.3–1.5 kg/(kgcatah) typically obtained in the commercially practiced methanol synthesis process. The biofuels from BGS possessed a high heat value of 40-42 MJ/kg. The selectivity toward C2+ alcohols (C2-C6) was obtained with a 70 wt%-90 wt % in alcohols products, and liquid hydrocarbons (C5+) in hydrocarbons products ranges from 60 wt%-71 wt%.The biofuels synthesis using the bio-oil reforming-based syngas (BRS) and the FeCuZnAlK catalyst mainly produced the liquid hydrocarbons, mixed alcohols and gas hydrocarbons within the investigated synthesis ranges: T=300-370 oC, P=5.0-7.0 MPa and GHSV=10000-20000 h-1. The maximum biofuels yield obtained from BRS was about 0.63 kg biofuels/(kgcat h) with a contribution of 0.40 kg alcohols/(kgcat h) mixed alcohols and 0.23 kg LHC/(kgcat h) liquid hydrocarbons within our investigated range. The heat value of the biofuels derived from the bio-oil reforming-based syngas was in the range of 35.27-37.28 MJ/kg, which waslower than that from the BGS.4. Investigation of some important elemental reactions and technology evaluation of bio-fuels via FT synthesis.Some important elemental reactions involved in the biofuels synthesis, including the water–gas shift reaction, reverse water-gas shift reaction, decomposition of alcohols and hydrocarbons, and methanation were also investigated in detail. Basic characters of the catalyst were also studied by XRD, ICP-AES, TPR and BET; the results contributed to the optimization of reaction parameters and understanding of reaction me