la mn双掺杂srtio3阳极材料制备及性能分析-preparation and performance analysis of la mn double-doped srtio _ 3 anode material.docxVIP

La，Mn 双掺杂 SrTiO3 阳极材料制备及性能研究 摘 要本文对溶胶-凝胶法合成固体氧化物燃料电池（SOFC）钙钛矿型 La，Mn 双掺杂 钛酸锶 LaxSr1-xMnyTi1-yO3-δ 阳极材料制备工艺及性能进行了研究。实验结果显示采用 柠檬酸为络合剂可以避免样品中出现 La2O3 杂相。根据溶胶凝胶前驱体的 TG-DTA 曲 线分析及 SEM 形貌扫描照片对比得出烧结工艺为 950℃保温 15h，得到了粒径为 10nm 左右的 LSMT 粉末样品，再烧结工艺定为 1350℃保温 12h，烧结后得到致密陶瓷结 构的 LSMT 阳极。探讨了 LaxSr1-xMn0.5Ti0.5O3-δ 随着 A 位掺杂量 （xx=0.1~0.5）及 La0.2Sr0.8MnyTi1-yO3-δ随着 B 位掺杂量 y（y=0.2~0.6），材料的性能的变化情况。通过 XRD 检测结果可知 利用溶胶-凝胶法制备得到的 LaxSr1-xMn0.5Ti0.5O3-δ 、La0.2Sr0.8MnyTi1-yO3-δ 系列样品均 为钙钛矿单相结构。x=0.5 时，有微小杂峰出现，SEM 测试证明粉末样品的粒度均匀， 粒径在 100nm 以内。但当掺杂量过大时，烧结后样品出现晶粒异常长大的现象。 LaxSr1-xMn0.5Ti0.5O3-δ （x=0.1、0.2、0.3、0.4）、La0.2Sr0.8MnyTi1-yO3-δ（y=0.2、0.3、0.4、 0.5 ） 系 列 样 品 的 相 对 密 度 都 在 90% 以 上 。 热 膨 胀 性 能 测 试 结 果 显 示 ， LaxSr1-xMn0.5Ti0.5O3-δ 系列样品随着 A 位掺杂的增加热膨胀系数先减小后增加，在 x=0.2 处取得极小值。而 La0.2Sr0.8MnyTi1-yO3-δ 系列样品随着 B 位掺杂量的增加，样品 热膨胀率逐渐降低。通过高温电导率测试及对电导活化能的计算，LaxSr1-xMn0.5Ti0.5O3-δ 、La0.2Sr0.8MnyTi1-yO3-δ 系列样品表现出典型的离子导电性。La0.2Sr0.8Mn0.5Ti0.5O3-δ 样品的高温电导率最高，800℃时达到 120.78S·cm-1。关键词：阳极材料，钙钛矿，SrTiO3，双掺杂，电导率iPREPARATION AND PERFORMANCE OF SrTiO3 ANODE MATERIALS DOPED WITH La AND MnABSTRACTIn this paper, the preparation by sol-gel method and electrical performance of La, Mn double doped SrTiO3 used for SOFC anode materials were investigated. The experiment results show that using citric acid as chelating agent can avoid samples appearing La2O3 mixed phase. According to the sol-gel former body tg-dta curve analysis and SEM morphology scanning picture contrast that particle size of about 10 nm LSMT powdersamples were obtained after annealed at 950 ℃ for 15h. Dense ceramic structure LSMTanode can be received after heating at 1350 ℃for 12 hours .The properties of LaxSr1-xMn0.5Ti0.5O3-δ and La0.2Sr0.8MnyTi1-yO3-δchanges with A bit doping quantity x（x=0.1~0.5）and B bit doping quantity y（y=0.1~0.5）were discussed. Theresults indicated that LaxSr1-xMn0.5Ti0.5O3- δ , La0.2Sr0.8MnyTi1-yO3-δ series of samples prepared by sol-gel method were a single phase of orthorhombic perovskite. With doping0.5 at A bit, small miscella