傅立叶变换红外发射透射ft-ir et光谱法在炭粒燃烧机理分析中的应用-application of fourier transform infrared emission transmission ft - ir et spectrometry in analysis of carbon particle combustion mechanism.docxVIP

傅立叶变换红外发 射/ 透射FT-IR E/T光谱法在炭粒燃烧 机理研究中的应用 摘要煤炭是我国的重要能源 燃烧是 目前煤炭利用的主要方式 为 了解决煤粉燃烧工程应用中存在的问题以及燃煤所带来的环境问 题 开发新的燃烧技术 实现人类社会可持续发展 人们需要进一 步深入了解煤粉燃烧的内在机理本文从弥散介质的辐射特性出发阐述了一种可同时获取颗粒表面温度和气相温度的在线测量技术傅立叶变换红外透射/发射FT-IR E/T光谱法通过与不同测温方法对蜡烛火焰酒精灯内焰以及高温粘土颗粒尘团测量结果的比较 表明了该方法测温的准 确性和优越性 辅以透光式微量给粉燃烧装置 捕捉 CO 在颗粒边 界层内被点燃所引起的颗粒温度迅速升高现象 从而用以研究颗粒 表面反应和气相反应的交互作用对煤粉/炭粒着火 燃烧燃尽的影 响实验测定了粒径为 90-125 ì m 炭颗粒 在不同环境气体温度条件 下 沿火焰不同高度的颗粒表面温度与气相温度 实验表明颗粒表 面的黑体因子在着火前后存在不同的变化规律 着火前颗粒表面的 黑体因子随颗粒温度升高而增大 着火后 该因子由颗粒温度 表面灰层及岩相物质相对含量的共同影响决定实验测得的颗粒表面温度与考虑 CO 在炭粒边界层内燃烧的连续膜模型预报结果符合得很好 而远高于不考虑 CO 燃烧反应的单膜 模型预报值 为 CO 在边界层内燃烧提供了有力的实验证明 指出 了 CO 燃烧对颗粒温度的巨大影响 为完善和开发更符合实际的煤炭粒燃烧模型提供了实验依据 而傅立叶变换红外发射/透射光 谱法FT-IR E/T作为一种富有潜力的实验手段将在煤粉燃烧的实 验研究中得到更加广泛的应用关键词炭粒FT-IR E/T燃烧着火APPLICATION OF FT-IR EMISSION/TRANSMISSION (E/T) SPECTROSCOPY TO STUDY CHAR COMBUSTION MECHANISMSABSTRACTCoal is the major energy resource in China, and burning is the primary way of coal utilization. In order to solve both practical and environmental problems raised by burning coal as well as develop new combustion systems for the sustainable development of human society, it is necessary to understand the mechanisms of pulverized coal combustion.Based on the radioactive characteristics of dispersive mediums, this paper develops a technique FT-IR Emission/Transmission Spectroscopywhich can be used as in-situ diagnostic technique to determine the temperatures of particles as well as individual gas species. Compared with several techniques in candle flame, alcohol burner inner flame and hot clay particles cloud temperature measuring, its accuracy and superiority has been proved. Accompanied with transparent wall reactor (TWR), this technique is employed to capture high char particle temperature caused by CO ignition in boundary layer, in order to studythe contributions of surface and gas phase reactions to coal/char ignition, combustion and burning off.The temperatures for char particles and gas phases along the TWR at different ambient gas temperature a