原位自生ti2alntial复合材料制备与高温性能研究-preparation and high temperature properties of in-situ autogenous ti _ 2 aln tial composites.docx

维网络结构的 Ti2AlN 增强体能够有效承载，明显提高了复合材料压缩强度。 摩 擦 磨 损 试 验 结 果 表 明 ： Ti2AlN/TiAl 复合材料 与 镍 基 合 金 组成 的 摩擦 副，室温摩擦过程主要分为两个阶段：I 阶段为非稳态摩擦阶段，镍基合金是 主要磨损方，磨损类型是镍基合金附着在复合材料磨面上的粘着磨损；II 阶段 为稳态摩擦阶段，镍基合金仍然是主要磨损方，磨损方式是 Ti2AlN/TiAl 复合 材料对其产生的磨粒磨损， 同时 Ti2AlN/TiAl 复合材料发生粘着磨损。室温 下，载荷增加，摩擦系数和磨损量均升高；滑动速度加快，Ti2AlN/TiAl 复合材料总磨损量增加，摩擦系数和复合材料的磨损率降低。 高温下摩擦副发生氧化，镍基合金氧化产物为 NiO，Ti2AlN/TiAl 复合材料的氧化产物为 Al2O3 和 TiO2。Ti2AlN/TiAl 复合材料-镍基合金高温摩擦过程 主要分为三个阶段：I 阶段为非稳态-摩擦系数上升阶段，镍基合金发生粘着磨 损；II 阶段为非稳态-摩擦系数下降阶段，镍基合金的磨损方式从粘着磨损向 磨粒磨损转变，复合材料磨损方式主要是粘着磨损；III 阶段为稳态-摩擦系数 平稳阶段，镍基合金是主要磨损方，磨损类型为磨粒磨损。高温下，随着滑动 速度增加，摩擦系数和复合材料磨损率均降低，复合材料的总磨损量上升；温 度升高，摩擦系数和复合材料磨损量均下降。不论在室温还是高温摩擦试验中，复合材料磨损量均低于 TiAl 基体合金，Ti2AlN 体积分数增加，复合材料 的磨损量随之降低。关键词：Ti2AlN/TiAl 复合材料；原位自生过程；高温氧化；热压缩； 摩擦磨损AbstractIn this paper, in situ Ti2AlN/TiAl composites were designed and fabricated. Microstructure and synthesis mechanism of Ti2AlN/TiAl composites were systematically investigated by scanning electron microscope(SEM), transmission electron microscope(TEM), X ray diffraction(XRD), differential scanning calorimetry(DSC) and so on. Properties of Ti2AlN/TiAl composites were tested by three-point bending, oxidation, hot compression and friction and wear, related factors were also analyzed.Ti, Al and TiN particles were raw materials, used hot-pressing technique to fabricated Ti2AlN/TiAl composites with 20% and 50% reinforcing phase volume fraction. the synthesis process of Ti2AlN/TiAl composites were divided into fourstages: the first stage began with Al completely melted(665℃), TiAl3 layer formedat Ti particles surface were the main new phase; in the second stage, Al powder/dict_result.aspx?searchword=%e5%8f%82%e4%b8%8eamp;tjType=sentenceamp;styleamp;t=participate%2Bin participated in synthesis reaction and were depleted, multilayer Ti-Al compounds bounding Ti particles, minor amounts of small-grained Ti2AlN particles formed atTiAl3 layer edge by liquation reaction; the third stage was at temperature 1100 ℃ to1300℃, the base material transformed into TiAl(the core