嵌段共聚物在选择性溶剂中自组装举动的研究.pdfVIP

摘 要 超分子自组装是近年来蓬勃发展的领域 通过自组装所获得的新型功能材料 在 高技术领域的应用已经显现出光明的前景 在高分子自组装领域中 对嵌段共聚物的 胶束化研究尤为广泛和深入 聚合物胶束是很好的药物输运 靶向载体 在水中可以 稳定存在的聚合物胶束因其对有机小分子有较强的吸附能力 可用于污水处理 环境 净化及微量成分的富集等 在其他领域的应用也日益广泛 生物体是自组装的体系 生命过程是自组装的过程 因此自组装的研究将为仿生成型提供方法和依据 利用末端带有反应性基团的PEO,反应生成末端带有苯胺基团的PEO,然后 引发 苯胺聚合 生成PAn-PEO-PAn 三嵌段共聚物和PEO-PAn 双嵌段共聚物 对其最佳的 合成条件进行了研究 通过FTIR TGA,DSC 等表征方法证实了所合成的是PAn-PEO PAn-PEO-PAn 嵌段共聚物 而不是各自均聚物的共混物 所合成的嵌段共聚物 PAn-PEO,PAn-PEO-PAn 通过动态激光散射测量表明 在选 择性溶剂DMF 中形成了胶束 它们的胶束半径在40-60nm 之间 对 PAn-PEO-PAn 三嵌段共聚物在选择性溶液中的自组装行为进行了研究 通过 SEM 我们系统的证实嵌段共聚物在选择性溶剂中缔合形成了中空的球状 柱状胶束 并且通过研究嵌段共聚物在溶剂中的缔合行为 我门知道其自组装受溶剂种类和浓度 的影响 关键词: 自组装 嵌段共聚物 自组装膜 胶束化 III Abstract In recent years, self-assembly of supramolecular developed rapidly. New-type functional material by self-assembly showed bright prospect in high technology. Aggregation of block copolymer was very important in self-assembly of supramolecular. Aggregation of copolymer was a very good carrier of medicine transportation and target. Because aggregation of copolymer existed stably in water, and had strong ability to absorb organic molecule, it was used to sewage disposal, environmental protection and collection of micro-composition, etc. In another aspect, self-assembly of supramolecular also had important application. All living-things were self-assembly systems and all life processes were self-assembly processes. Self-assembly of supramolecular would provide theories and methods for Bionic Manufacturing. PEO with aniline was synthesized by PEO reacting with p-Phenylenediamine. Then diblock copolymer PAn-PEO and triblock copolymer PAn-PEO-PAn were synthesized by copolymerization o