郑州大学毕业设计轻质高铝隔热材料的制备.docVIP

郑州大学毕业设计（论文） 题 目： 轻质高铝隔热材料的制备 The preparation of high-alumina lightweight Insulation Materials 指导教师： □□ 职称： 教授 学生姓名： 王□□ 学号： 200xxxxxxxx 专 业： □□□□ 院（系）： □□□□ 200x 年 x 月 x 日摘要 本文以α-Al2O3粉、蓝晶石、焦宝石为原料，选择聚苯乙烯球为造孔剂，采用注浆成型制备轻质高铝隔热材料。试验主要研究了烧成制度（烧成温度）、造孔剂对制品性能的影响。借助SEM、XRD、平板导热仪及其它设备对材料显微结构、矿物相及常温物理性能进行检测并分析，得出最佳的烧成制度、造孔剂加入量。研究烧成制度对试样性能的影响，结果表明：在1450℃下保温3h，试样烧后有良好的常温物理性能，其内有大量交错的柱状莫来石生成。在造孔剂的选择方面，主要研究了添加量对制品性能的影响。研究表明，当聚苯乙烯球添加量为100%时，试样体积密度为0.722g/cm3，导热率为0.33W/(m·K)。焦宝石的添加提高了试样高温烧结性能。蓝晶石对于轻质高铝砖来说是很好的膨胀剂，在高温下易生成莫来石，抵消了因造孔剂烧失与砖内组织烧结引起的烧后收缩。通过优化工艺与配方，添加100%的聚苯乙烯球，采用挤压成型，经1450℃×3h烧成，可制出体积密度0.722g/cm3、导热率为0.33W/(m·K)、烧后线变化小于5%、常温耐压强度最大可达1.8MPa的轻质高铝砖。 关键词：隔热材料；高铝；造孔剂；烧结性能 Abstract In the paper, the preparation of lightweight brick of high alumina using α-Al2O3, distrene, flint clay and polystyrene ball is investigated with slip casting. the effect offiring system(firing temperature), the amount of pore-making agent on the properties of samples is carried out. Furthermore, optimum firing temperature, amounts of pore-making agent wasconfirmed by means of SEM and XRD. The effect of firing system on the properties of samples was studied. When the sample issintered at 1450℃for 3h, the results showed that samples are of good physical performance, which form a amount of crossing cylindrical mullite.In the aspect of selecting pore-making agent, the results show that a proper amount of additive will be advantageous to produce porosity of uniform distribution. When the amount of polystyrene bubble is 100 percents respectively, bulk density of sample is 0.722g/cm3. The coefficient of heat conductivity is 0.33W/(m·K). Flint clay promotes the ability of sintering. Distrene is a kind of good expanding agent for lightweight bricks of high alumina, which will produce mullite after sintering which will offset the shrinkage of samples because of the ignition loss of pore-making agent and the sintering of clay.