玻纤增强耐高温液晶聚酯的增韧改性.docVIP

玻纤增强耐高温液晶聚酯的增韧改性(LCP)这一种新型的工程塑料，具有高强度、高刚性、耐高温、电绝缘性等优良性质，被用于电子、电气、光导纤维、汽车及宇航等领域。针对LCP韧性比较低的缺陷，使其韧性增强是国内外研制开发新型工程塑料的一个努力方向。 液晶聚酯具有较高的熔融温度，对增韧剂要求较高。相比较，用弹性体增韧的增韧效果最好。弹性体增韧液晶聚酯应具有的结构特征:液晶聚酯为连续相，弹性体为分散相;弹性体适度交联和基体间有化学键连接。 本工作以液晶聚酯为基体树脂，研究三元乙丙弹性体(EPDM)和/或聚乙烯辛烯共弹性体(POE)为增韧剂，通过双螺杆挤出机熔融反应挤出，用马来酸酐使POE酸酐化生产接枝共聚物POE-g-MAH；然后，把接枝好的POE-g-MAH加到液晶聚酯中，用双螺杆挤出机造粒、注射机制样，制备了LCP/ POE-g-MAH共混的样条，研究了LCP/POE-g-MAH=90/10、80/20、70/30、60/40、50/50（质量比）共混的冲击、拉伸强度等性能的影响。 结果表明：POE对液晶聚酯有一定的增韧作用，提高了树脂的冲击强度，但是POE的用量也不是越多越好，POE达到一定的程度后，增韧的作用将降低，而且还会影响其他性能。 关键词：马来酸酐；接枝；液晶聚酯；增韧母料； 增韧结构性能 Toughening of glass fiber reinforced heat-resistant LCP Liquid crystal polymer (LCP) that a new engineering plastics, high strength, high stiffness, high temperature, good electrical insulation properties, etc., are used in electronic, electrical, fiber optics, automotive and aerospace industries. LCP toughness for low defect, to enhance toughness is developed at home and abroad a new direction for engineering plastics.  This work was designed to show a good rigid liquid crystal polyester elastomer toughened structural characteristics should be: for the continuous phase liquid crystal polyester, elastomer is dispersed; elastic appropriate crosslinking. And there are chemical bonds between the matrix. To achieve the above design ideas, and get better technical and economic ratios, the work initially as matrix liquid crystal polyester resin, EPDM elastomer (EPDM) and / or polyethylene-octene elastomer total (POE) to increase Ren agent, by twin-screw extruder melt extrusion, so POE with maleic anhydride graft copolymer anhydride production POE-g-MAH; then, to graft good POE-g-MAH added to the liquid crystal polymer ester, the use of twin-screw extruder granulation, injection mechanisms like, prepared LCP / POE-g-MAH blend spline, of the LCP / POE-g-MAH = 90/10, 80/20, 70/30, 60/40, 50/50 (mass ratio) blends of impact, tensile strength and other properties.  The results showed that: POE on the liquid cryst