石墨烯的制备及其在化学电源中的应用研究-化学工程与技术专业论文.docx

下载文档 降价啦

6
0
约13.53万字
约 163页
2018-06-28 发布于上海
举报
版权申诉
保障服务

石墨烯的制备及其在化学电源中的应用研究-化学工程与技术专业论文.docx

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。

石墨烯的制备及其在化学电源中的应用研究-化学工程与技术专业论文

AbstractAsthemembersoftheNew-typechemicalpowersources,Lithium-ionbatteries,ElectrochemicalcapacitorsandFuelcellshavetheirowncharacteristicssothattheybecomethehotspotsoftheresearchesonNew-typepowersources.Andtheindispensablecomponentinabovesystemsisthecarbonmaterial.ThegraphenecarbonmaterialwiththedistinctperformanceshasapromisingapplicationprospectsintheNew-typechemicalpowersources.Inthispaper,themainpartisabouttheresearchesontheLiMnPO4cathodematerialforLIB,MnOanodematerialforLIB,Lithium-ioncapacitorandtheelectrocatalystforFuelcell.Inaddition,thegraphenecarbonmaterialisalsoappliedtoimprovetheelectrochemicalperformancesofthematerialsmentionedabove.AnditmakesanexplorationontheapplicationprospectsforgrapheneintheNew-typechemicalpowersources.Inthiswork,itfirstlyintroducesthesynthesisprocessesofgrapheme,includingtheoxidation-reductionrouteanddirectlow-temperatureshock-heatingprocess.Asfortheoxidation-reductionroute,itusesthegraphiteoxideastherawmaterialandNaBH4asthereducer.Andtheacquiredgraphene,whichisthefew-layergraphenewithwrinkledorcurvedmorphology,haslagerproportionofCsp3inthegraphenesheetsandprovidesaBETspecificsurfaceareaof296m2g-1.Besidesthat,adirectlow-temperatureshock-heatingprocess,whichismuchmoresuitableforthemassproductionofgraphene,issuccessfullydevelopedforthefirsttime.Theacquiredgrapheneviatheheat-treatment,whichisalsothefew-layergraphene,haslagerproportionofCsp2inthegraphenesheetsandprovidesasatisfiedBETspecificsurfaceareaof421m2g-1.Inaddition,commercialGraphenenanoplates(GNPs)isanothercandidateforapplicationintheresearchwork.Anditstillmaintainsthehighlyorderedstructureofthegraphitebuthasmuchfewerlayers(around3-11layers)thanthegraphite.TheGNPswiththenonuniformdistributionofsheetsizeandthicknessprovidesaBETspecificsurfaceareaonlyabout22m2g-1.ThepreparationandmodificationofLiMnPO4cathodematerialandtheapplicationofGNPsarealsostudiedindetailinthispaper.ThepreparationmethodsofLiMnPO4cathodematerialaretheprecipitationprocessandnovelsol-gelmethod.Duringthepreci