丙烯酸酯乳液的合成及膨胀型防火涂料的制备与分析-synthesis of acrylate emulsion and preparation and analysis of intumescent fire retardant coating.docxVIP

ABSTRACTAcrylates emulsion has acquired an important application in fire retardant coating. Three main contents are researched in this paper. Synthesis of new type acrylates, discuss the influence of acrylate emulsion on properties of fire prevention, exploring the influence of nano magnesium hydroxide on the performance of the fire coatings.A new acrylates emulsion with hard core and soft shell structure was prepared by designing partical structure forming. The influence of monomer, the proportion and the amount of emulsifier, the content of initiator, the technology of polymerization and the temperature on the acrylates emulsion were studied. In this paper, tests showed that the performance of modified emulsion got a prominent improvement in water resistance, mechanical properties, low cured temperature and excellent adhesive ability.The water-based intumescent fire retardant coating was prepared by using ammonium polyphosphate as acid source, pentaerythritol as carbon source, dicyandiamide and diammonium phosphate as blowing agent, thermoset-epoxy emulsion and acetate latex as binder. Flame-retardant performance of the coating was investigated by simulated big panel combustion method, FTIR was used to analyse the ingredient of the charring layer. And the char residues were observed by scanning electron microscope (SEM). The results showed that epoxy emulsion has positive influence on fire-retardant and heat-insulation performance. When content of epoxy emulsion was 9 wt%, the back temperature of testingboard was only 61℃ after 60 minute ignition, strength of the charringlayer reached at 3.22 N /cm2, and the expand ratio was 36, the FTIR shows that binders exist between the conjunction of char and plank. Observation of SEM shows that the charring layer of the intumescent fire retardant coating became better after mixing epoxy emulsion.In the binder of the fire coating performance impact, binder in the expansion of the important position of fire coatings, through t