卟啉试剂的合成及界面电化学性质的分析-synthesis of porphyrin reagent and analysis of electrochemical properties at interface.docxVIP

§2.2.1 试剂 .............................................................................................................. 23§2.2.2 仪器和测试条件 .......................................................................................... 23§2.2.3 系列邻甲氧基羟基苯基卟啉的合成和表征 ............................................... 24§2.2.3.1 系列邻甲氧基羟基苯基卟啉的合成 ....................................................... 24§2.2.3.2 系列邻甲氧基羟基苯基卟啉的表征 ....................................................... 25§2.2.4 系列不同碳链长度的单巯基尾式卟啉的合成和表征 .............................. 32§2.3 巯基苯基卟啉的应用及其自主装膜的表征 ................................................. 37§2.4 小结 ...................................................................................................................................... 41参考文献 .................................................................................................................... 42§第三章三甲氧基羟基卟啉及其巯基卟啉的合成和自主装膜电子转移的研究 44§3.1 引言 ................................................................................................................. 44§3.2 实验部分 ......................................................................................................... 44§3.2.1 试剂 .............................................................................................................. 44§3.2.2 仪器及测试条件 .......................................................................................... 44§3.2.3 5-(4-羟基苯基)-10, 15, 20-三(4-甲氧基)苯基卟啉的合成和表征 ............. 45§3.2.3.1 5-(4-羟基苯基)-10, 15, 20-三(4-甲氧基)苯基卟啉的合成 ..................... 45§3.2.3.2 5-(4-羟基苯基)-10, 15, 20-三(4-甲氧基)苯基卟啉的表征....................... 46§3.2.4 系列不同碳链长度的单巯基尾式卟啉的合成和表征 .............................. 50§3.3 巯基苯基卟啉自主装膜的电子转移研究 ..................................................... 56§3.4 小结 ................................................................................................................. 58参考文献 .................................................................................................................... 59§第四章 系列硝基苯基卟