磁铁矿精矿酸浸—矿浆萃取脱磷工艺-acid leaching of magnetite concentrate - pulp extraction dephosphorization process.docxVIP

AbstractPhosphorus is one of the harmful elements commonly existed in steel smelting. The iron and steel was brittle and easily broken when cooled for the presence of phosphorus, which greatly affected the quality of pig iron and steel. Recent years, with the rapid development of economy, science and technology, the demand of steel material with special performance was increasing, and the requirments of iron ore(iron concentrate), which is the raw material of iron and steel production, was also improved gradually. Therefore, suitable methods of sorting and treating high phosphorus iron ore to get low phosphorus iron concentrate was the urge demand for the use of high phosphorus iron ore, which has huge reserves in China.The paper first summarized current methods and studies on the removal of phosphorus from phosphorus iron ore(iron concentrate), and then according to the analysis of occurrence characteristics of phosphorus and phase distribution of ferrum, acid leaching method was proposed to remove phosphorus from magnetite concentrate, which were the raw materials of high purity pig iron production of a company. The dephosphorization ratio reached 95.5% at the optimum experimental conditions of acid leaching dephosphorization: grinding fineness -0.074mm 90.5%,the dosage of hydrochloric acid 92 kg/t, pulp density 50%, reaction temperature 25 ℃,reaction time 2 h, stirring speed 100 r/min。In the reuse experiment of acid leaching solution, it was found the adsorption of phosphate onto magnetite surface was occurred, this kind of adsorption led to the reduction of dephosphorization effect, and the adsorption capacity increases with the increase of phosphorus in solution.In this study, solvent-in-pulp extraction was first applied on the removal of phosphorus, the target of solvent-in-pulp extraction was to inhibit the adsorption of phosphate onto magnetite surface and proceed the chemical reaction of dephosphorization by extracting phosphate from leaching solution to th