贵州省沿河县土壤及特色农产品硒锌锗调查分析-investigation and analysis of selenium, zinc and germanium in soil and characteristic agricultural products in yanhe county of guizhou province.docxVIP

贵州省沿河县土壤及特色农产品硒锌锗调查分析-investigation and analysis of selenium, zinc and germanium in soil and characteristic agricultural products in yanhe county of guizhou province.docx

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贵州省沿河县土壤及特色农产品硒锌锗调查分析-investigation and analysis of selenium, zinc and germanium in soil and characteristic agricultural products in yanhe county of guizhou province

PAGE PAGE 4 4. 黑水乡杨寨村、土地坳镇安坡村的茶叶,谯家镇桂鲜村的洋芋含硒量较高, 黄土乡简家村的茶叶,和平镇谢家村的番茄含锌量相对较丰富,沙子镇的空心李, 和平镇谢家村的番茄含锗量均较高。谯家镇长征村洋芋硒、锌、锗含量均较高。 其他采样点农产品硒、锌、锗含量属适中范围。 5. 土壤中的锌含量与农产品中的锌含量相关性显著,可以通过调节土壤中的锌 含量来控制农产品中的锌含量。土壤中硒 、锗含量与农产品中硒 、锗含量也有 一定的相关性但相关不密切,相关系数分别为0.371、0.202。 本试验原子荧光测定土壤中硒、锗最佳条件的探讨为硒、锗的测定提供了试 验依据。试区样点土壤及特色农产品硒、锌、锗的含量的分析对开发富硒、富锌、 富锗农产品及实现因地种植提供了理论依据。 关键词:贵州省 沿河县 土壤 特色农产品 硒 锌 锗 空间分布 相关性 Abstract 219 soils and 22 agricultural products located in Yanhe county were sampled by GIS technology for analysiing their selenium,zinc,germanium content, To achieve the possibility of selenium,zinc,germanium-rich agricultural products and elements relationship between soil and agricultural products, the statistical principles and methods were used to study spatial distribution of soil selenium,zinc,germanium. The main conclusions are as follows: Selenium and germanium in soil were determined by atomic fluorescence spectrometry AFS2820, the work condition of apparatus respectively of negative high voltage are 300 V and 270 V, A road lamp current are 90mA and 80mA, atomizer temperature are all 200 ℃, carrier gas flow rate are 400mL/min and 300mL/min, shielding gas flow rate are all 1000mL/min. The results indicate that the test with high sensitivity and high precision, accuracy, and is fast, simple, less matrix interference, low detection limit, the advantages of good reproducibility. Determination of the method the results of standard materials in good agreement with standard values, selenium and germanium, the relative standard deviation respectively are 0.65% and 0.98%, and the detection limit are 0.34μg / L and 1.15 μg / L, recoveries are 98.4% ~ 102.0% and 90.0% ~ 104.7%. Selenium, zinc, germanium content range of soil in Yanhe county are: 0.14 ~ 1.82mg/kg, 42.6 ~277.3mg/kg, 1.01~4.21mg/kg respectively. the average concentration are 0.498mg/kg, 86.31 mg / kg, 2.168 mg / kg respectively. Combination of mean and median, the selenium content is moderate district. Zinc content i

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