高粘性耐热型聚氨酯胶粘剂的合成分析-synthesis and analysis of heat-resistant polyurethane adhesive with high viscosity.docxVIP

中北大学学位论文中北大学学位论文Synthesis and Research of High Viscosity and Heat-Resistant Polyurethane AdhesivesAbstractPolyurethane adhesive has the characteristics of higher strength, higher wearing resistance, low temperature resistance, oil resistance, corrosion resistance to chemicals, etc. Since 1930s, it has been applied widely in various fields. At same time, its shortcoming of poor heat resistance has arisen. Melamine is a nitrogen heterocyclic organic compound, which has the stable structure of benzene rings and contains a π bond in the molecular. Melamine has a relatively high melting point and is not easy to decompose. Polyurethane adhesives with melamine will have the characteristics of heat resistance.In the paper, the method of prepolymerization had been adapted in the process of synthesis. Polytetrahydrofuran glycol (PTMEG) was the soft segment, HYPERLINK /bioondb_MSDS_list.html?enname=iso isophorone HYPERLINK /bioondb_MSDS_list.html?enname=iso diisocyanate (IPDI) was the hard segment, dibutyltin dilaurate (DBTL) was a catalyst, MOCA (4,4-Methylene bis(2-chloroaniline)) and HYPERLINK /bioondb_MSDS_list.html?enname=1%2C4 1,4-butylene glycol (BDO) were used as the chain extension agent respectively, and melamine was added, then the ammonia methyl silicone had been implanted in PTMEG polyurethane .The L9(34) orthogonal experiment method was used to decide the better processconditions and formulations in the experiments. The structure and performance characterizations of synthetic products were determined by using FTIR infrared spectrum, TG (differential thermal scanners) and ultraviolet spectrum. The tests of peel strength and elongation at break for the polyurethane adhesives film had been also measured. The results show: when BDO was as the chain extension agent, melamine was as the modifying agent and ammonia silicone fluid was as end-capping reagent, the optimum technology conditions for PTMEG polyurethane adhesive were: the reaction time was 6 hour