纳米结构lifepo4c正极复合材料的制备及其掺杂改性-preparation and doping modification of nanostructured life po 4c cathode composite material.docxVIP

I II Abstract As the most potential cathode material, LiFePO4 has incomparable characteristics. But its intrinsic electronic conductivity and the diffusion rate of Li+ in the material internal structure are very low. This will affect the electrochemical properties of material in the charging and discharging process, and lead to irreversible capacity loss. In this paper, those question will be studied in detail. The main research work and conclusion are summarized as follows. LiFePO4/C nanocomposite materials are synthesised by the sol-gel method from LiOH, FePO4/PANI which prepared by in situ polymerization method and citrate which used as carbon source and chelating agent. The morphology and structural characterization of materials were characterized by SEM and XRD, and the results show that the samples have olivine type crystal structure with pure phase. The particle size is within the scope of the 40-60 nm, which shows that a certain amount of carbon source can effectively limit the growth of crystal in the process of synthesis of LiFePO4/C composites. After the synthesis of LiFePO4/C composites by sol-gel method, how the sintering temperature and the citric weight affect on the morphology structure and electrochemical performance of the cathode materials are studied by cyclic voltammetric curve, electrochemical impedance spectrum and the charge and discharge curves of the samples. It is found that the sampls prepared at 650 ℃ and with the molar ratio n (LiFePO4) : n (citric acid) = 1:0.7 displays the best electrochemical performance. The electrochemical test results show that the samples exhibits the initial discharge capacity of 165.8, 157.7, 149.2, 132.4, and 92.8 mAh·g-1 at 0.2, 0.5, 1, 2 and 5 C,repectively. After 31cycles, it retains discharge capacity of 165.0, 156.5, 146.4, 132.2 and 88.4 mAh·g-1. In the study of modified LiFePO4, Mn was doped in place of Fe-site of LiFePO4, and the effect of doping the amount of Mn to the material structure and electroc