室温离子液体基金 银纳米流体的制备及其在电研究化学中的应用-preparation of room temperature ionic liquid-based silver nanofluids and their application in electroanalytical chemistry.docxVIP

Preparationofgoldandsilvernano-fluidbasedonroomtemperatureionicliquidanditsapplicationinelectroanalyticalchemistryAbstract:Nanofluidswasproposedin1995,whichhavebeenwidelyusedinmanyfields.TheConventionalmediumsofnanofluidsmostlyarewater,oilandethyleneglycolandsoon.However,thesemediumshavethedrawbacksofvolatileandbadthermalstability.Moreover,thevolatilemediumswillcauseairpollution.Theionicliquid,asatrulygreensolvent,widelyattractstheattentionofscientists.Inviewofbetterthermalstabilityandthermalresistance,somescholarsbegintoresearchonpreparingnanofluidswiththeionicliquidasbasefluid.Inthisexperiment,thegold,silvernanofluidsusingionicliquid[BMIm]PF6asthemediumwasprepared.Thesizeofnanoparticlesandthestabilityofthenanofluidswasdiscussed.Ionicliquidshavegoodconductivityandabroadelectrochemicalwindow,andthenoblemetalnanoparticleshaveawidesurfaceareaandgoodelectricalconductivity,bothionicliquidsandnoblemetalnanoparticleshavebeenwidelyusedinconstructingelectrochemicalsensinginterface.But,thestudyofpreparingsensorbyusingnanofluidtomodifyingelectrodeisreportedrarely.Inthisexperiment,theionicliquid-basedgoldnanofluidswasusedtomodifytheglassycarbonelectrodeforpreparingtheelectrochemistrysensor.Thissensorwasusedforthedeterminationofuricacid(UA).Itdevelopsthenewapplicationofnano-fluidsinthefieldofelectroanalyticalchemistry.Themaincontentsandresultsaredescribedasfollows:Intheionicliquid/watertwo-phasesystems,theAg+wasextractedfromaqueousphasetoionicliquidphasebytheextractantdithizone.Ag/[BMIm]PF6nanofluidwassynthesizedbytheultrasound-assistedreductionofAg+inionicliquidphase.Thenanofluidpreparedwascharacterizedbynano-particlesizeanalyzer,transmissionelectronmicroscope,andfouriertransforminfraredspectrometer.Theresultsshowedthatthemeandiameterofthenanoparticleswasabout11nmandthenanoparticlesweredistributedevenlythroughouttheionicliquid.Dithizonenotonlyeffectivelypreventedthenanoparticlesfromagglomerationandoxidation,butalsoenhancedthesolubilityofthenanoparticlesinionicliquids,whichcont