湿式氧化降解β-萘磺酸钠模拟废水的分析-analysis of simulated wastewater from wet oxidation degradation of β -naphthalenesulfonic acid sodium salt.docxVIP

AbstractNaphthaleneSulfonatewhichiswidelypresentinbiological,pharmaceuticalproducts,dyesandotherindustriesisaveryimportantfinechemical.However,intheproductionprocessnaphthalenesulfonateproductswillproducealotofwaste.ThesewastesarenotonlyhavinghighCODandcolorbutalsoverydifficultinbiodegradation.Itisconsideredasamajorchallenge,athomeandabroad,forEnvironmentalResearchCommunitytodevelopmentmethodswhichshouldbeeconomicalandpracticalforthehandlingoftheseby-productsofnaphthalenesulfonicacid.Inthispaper,removalofβ-naphthalenesulfonatewasstudiedasatargetcompoundonwetoxidationprocess.Inthisstudy,theCODremovalastechnicalindicators.First，Studyontheprocessconditionsofthewetoxidationprocessβ-naphthalenesulfonatesimulatedwastewater.Thestudyfound，Thereactiontemperaturehasadirecteffectontheimpactofwastewatertreatment,Whenthereactionreachedthedesiredtemperature,thehigherthetemperature,fasterwouldbethereactionrate.Thebestoptimizedtemperaturewasfound250℃.Theeffectofoxygenpartialpressureonwastewatertreatmentwasstudiedandfoundthatitsinfluenceisalsomoreobvious.Whenoxygenispresentinlargequantity,thereactionratewouldbequicker.Alkalineconditionfavorsdegradationofβ-naphthalenesulfonatethanthestrongacidicconditions.AppropriateincreaseinthestirringratecanaccelerateofthereactionandimprovetheCODremoval.1.00~4.00g/Lwasoptimizedconcentrationforremoval,Thehighconcentrationofwaterislessidealforremoval.Accordingtotheexperimentalresults,themostoptizedconditionswere;temperature250℃,theoxygenpartialpressure2.0MPa,theinitialpHvalueof8.00,thestirringrate400r/minandtheinitialwaterconcentration4.00g/L.Underoptimalconditions，after60minofreactiontime,CODremovalwasupto80%,Useofsemi-empiricalmathematicalmodelforthedegradationoftheseineachsinglefactor,dynamicsfittheexperimentaldata.Togetabetterfitinakineticequation,itsuggesttheapplicationofmathematicalmodelofengineering.Inadditiontooptimizedconditions,β-naphthalenesulfonicacidsampleswerefurtherstudiedbyliquidchromatography-massspectrometry(LC-MS)fortheconfirmatio