细乳液聚合制备纳米改性聚氨酯-丙烯酸酯复合乳液及其性能分析-preparation and performance analysis of nano-modified polyurethane-acrylate composite emulsion by miniemulsion polymerization.docxVIP

细乳液聚合制备纳米改性聚氨酯- 细乳液聚合制备纳米改性聚氨酯-丙烯酸酯复合乳液及其性能研究 PAGE PAGE iv particle size distribution; Besides, the water-absorbing ratio, pull extensor strength and TG tests showed that nano- TiO2 can increase the water resistance, weather resistance and tensile strength of the poly- mer. In the third section of the dissertation, polymer/SiO 2 nanocomposite particles were prepared by the double in situ miniemulsion polymerization method in the presence of surfactant (sodium dodecyl sulfate), costabilizer (hexadecane), methyl methacrylate (MMA), butyl acrylate (BA), and silica precursors (tetraethoxysilane, TEOS). The formation of SiO 2 particles and the polymerization of organic monomers took place simultaneously. A silane coupling agent, ?-methacryloxy (propyl) trimethoxysilane (MPS), was used as a functional comonomer to chemically link the polymer and inorganic silica via the copolymerization of MPS, MMA, and BA. The morphology of nanocomposite particles was characterized by transmission electron microscopy (TEM). The microstructure, mechanical properties, thermal properties, and optical properties of the as-prepared films were characterized by scanning electron microscopy (SEM), materials testing machine, thermogravimetric analysis (TGA), and UV-vis spectroscopy, respectively. The results showed that the P(MMA-BA)/SiO 2 nanocomposite particles had a raspberry-like structure with nano-silica chemically adsorbed onto the polymer microspheres. The ultrafine silica particles of about 20 nm were highly dispersed within the nanocomposite films and the transmittance of the nanocomposite film was comparable to that of the copolymer latex film at around 70–80 % from 400 to 800 nm. The mechanical properties and the fire retardant behavior of the polymer matrix were improved by the incorporation of nano-silica. In the fouth section of the dissertation, first, The polyurethane (PU) prepolymer was prepared by condensation of isophorone diisocyanate and polyethylene glycol using 1,4-buta