(Sm,Nd)SrMnO作为SOFC阴极材料的性能研究凝聚态物理专业论文.docxVIP

哈尔滨工业大学理学硕士学位论文 哈尔滨工业大学理学硕士学位论文 Abstract Solid Oxide Fuel Cells （ SOFC ） was considered as a promising fuel cell because it is a kind of electricity generator with high efficiency and low pollution. As the key element of SOFC, in the performance of the whole cell, cathode plays a very important role. Its structure, character and mechanism of reaction will affect behaviors of transmiting oxygen ions and electrical condu ctivity. For the further improvement of cell performance, the developmenting high performance and novel cathode material is crucial.At present, SOFC operate commonly at about 1000℃. So it makes great sense to develop novel pattern of cathode materials with higher ion and electrical conduetivity at intermediate temperature. The perovskite-like A2 BO 4 type oxide materials displ ayed mixed ionic and electronic conducting properties, substantial oxygen permeability, high electrochemical performance, and a relatively high oygen diffusion and surface exchange coefficients. In this thesis , the cathode material Sr2-x Lnx MnO 4(Ln=Sm,Nd) , x=(0, 0.1, 0.3, 0.5, , 0.9) was synthesized by the sol-gel method. we studied the properties such as the crystal structure, the chemistry compatibility of the electrode and electrolyte , the match of TEC, intensity, TG, electrical conductivity and activation energy of sample; investigated the microstructure, porterties sintered of sample, we determine the optimum sinter ing temperature. appling ma terial to half cell, we studied the output characteristic. we come to the conclusion that both electrovalent balance and solid solubility determine the cause shaping the struture of A2BO4 at x=0.3, 0.5. The sample has a good chemical compatibility with the GDC(Ce 0.9 Gd0.1 O1.9 ) within 1100 ℃.In air, TEC of GDC was 17.7×10-6 K-1 and sample was 17.7-19.3 ×10-6 K-1 , exhibiting the similar thermal expansion properties in the temperature range of 200- 900℃.The loss of weight