TZ3Y20A-SrSO4陶瓷基复合材料的制备-材料学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - 磨损速率室温下在 6.33×10-5~6.91×10-5mm3/N·m之间，在 600~800oC时位于 1.17×10-5~3.39×10-5 mm3/N·m 之间。经高温磨损试验后，复合材料中的 SrSO4在磨损表面分布均匀，在宽温度范围内起到了固体润滑作用，有效地 改善了高温陶瓷的摩擦学性能。 关键词 TZ3Y20A-SrSO4 陶瓷基复合材料；SrSO4 纳米粉体；摩擦学性能； 热压烧结；放电等离子烧结 - - PAGE IV- Abstract Nanoscale SrSO4 powders were prepared by chemical precipitation method. ZrO2(3mol%Y2O3)-20wt%Al2O3(TZ3Y20A) ceramic was selected as the matrix due to its high melting point, excellent mechanical properties and wear-resistance. TZ3Y20A-SrSO4 ceramic matrix composites were fabricated by hot-pressing sintering and HYPERLINK /dict_result.aspx?searchword=%e6%94%be%e7%94%b5%e7%ad%89%e7%a6%bb%e5%ad%90%e7%83%a7%e7%bb%93amp;tjType=sentenceamp;styleamp;t=spark%2Bplasma%2Bsintering spark plasma sintering, respectively. The morphology and growth mechanisms of nanoscale SrSO4 crystals and microstructure of TZ3Y20A-SrSO4 composites were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and differential scanning calorimetry-thermogravimetry (DSC-TG) measurement. The mechanical and tribological properties of TZ3Y20A-SrSO4 composites were studied by universal testing machine and high temperature friction and wear tester. The nanoscale SrSO4 particles prepared by chemical precipitation method have different morphologies, including flake-like, rod-like and equiaxed shapes. The flake-like SrSO4 particle has a thickness of 100 nm and a length of 200 nm. The rod-like SrSO4 particle has a diameter of 80~150nm and a length of 700~800nm. However, the particle size of equiaxed shape SrSO4 crystal is about 80nm. The diffraction intensity ratio of two low-energy crystal planes of (002) and (210) shows that, different crystal planes exhibit different growth rates, which may directly lead to the formation of flake-like and rod-like SrSO4 crystals. However, the driving force of SrSO4 crystal growth was dispressed with d