成核剂对pppoe共混体系结晶行为的影响-effect of nucleating agent on crystallization behavior of pppoe blends.docxVIP

II II ABSTRACT Modification of PP by adding nucleating agents is an important way to improve the performance of PP resin. It can significantly improve the properties of crystallization and mechanical properties. Many studies demonstrated that there is significant synergy effect about nucleating agents consisting of inorganic, organic or other different structure substance. In order to make use of the advantages of a variety of nucleating agent, development of multi-component composite nucleating agent is an important trend for the modification of PP. A series of NF composite nucleating agent was prepared based on low molecular weight PA6 powder in this paper. The effect of NF composite nucleating agent on the crystallization properties and morphology of polypropylene ethylene-octene copolymer blends was investigated by means of differential scanning calorimetry, polarizing optical microscope, ARES advanced rheometer etc. We discussed crystallization kinetics of the modification of PP using NF composite nucleating agent by Avrami equation and LH theory. The results show that NF series nucleating agent have certain nucleation effect on PP/POE blends, they have varying degrees of impact on the crystallization rate, crystallization temperature, half peak width and crystallinity. Three of the NF series nucleating agents (NF-6, NF-9, and NF-10) have remarkable improved integrated effect. The effect of the amount of nucleating agent on the crystallization behavior of PP/POE blends: when the amount of nucleating agent is gradually increased from 0% to 0.6%, the crystallization properties of polypropylene blends improved significantly and the trend is very clear, while the amount of nucleating agent is more than 0.6%, crystallization temperature and crystallization rate changed slightly.Adding nucleating agents into PP/POE blends improved the crystallization properties. After adding NF-14, the crystallization temperature of PP/POE blends increased from 117 ℃ to 131