多色荧光硅纳米颗粒的制备以及在白光LED光转换层中的基础应用分析-材料学专业论文.docxVIP

I I 多色荧光硅纳米颗粒的制备以及在白光 LED 光转换层中的基础应用研究 中文摘要 中文摘要 近年来，小尺寸（2.5-5 nm）荧光硅纳米颗粒因其独特的光学性质（如，强且 稳定的荧光）和良好的生物相容性，被广泛研究并用于光学应用。本文中，利用 荧光硅纳米颗粒作为新型光转换器，我们介绍了一种基于小尺寸（~3.7 nm）荧光 硅纳米颗粒的光转换器用于构建新型白光发光二极管（light-emitting diodes， LEDs）。我们优化了之前报道的微波辅助合成荧光硅纳米颗粒的方法，通过调控反 应前体溶液的 pH 值（从碱性调整到酸性），制备得到光色可调的荧光硅纳米颗粒 （从蓝光到黄绿光），最大发射波长从 454 nm 调整到 545 nm。特别地，在前体溶 液 pH 值为 4 条件下制备得到的荧光硅纳米颗粒呈现黄绿色荧光，且发射峰较宽， 适合于白光光谱的构建。进一步地，我们将其作为光转换器并用于构建白光 LED。 制备得到的 LED 的流明效率为 13 lm/W，CIE（Commission Internationale de lEclairage）指数为（0.3041，0.3129），CRI（Color Rendering Index）指数为 82， 色温指数为 7982 K。 关键词：荧光硅纳米颗粒；荧光可调；光转换器；白光 LED 作 者：杨柳 指导老师：何 耀 教授 II II Abstract Fluorescent Silicon Nanoparticles Utilized As Stable Color Converters for White LEDs Fluorescent Silicon Nanoparticles Utilized As Stable Color Converters for White Light-Emitting Diodes Abstract Small-sized (2.5-5 nm) fluorescent silicon nanoparticles (SiNPs) are being intensively studied and explored for various optic applications to take advantages of their relatively strong fluorescence and favorable biocompatibility. In this study, by employing fluorescent SiNPs as a new class of color converters, we introduce a type of small-sized (~3.7 nm) SiNPs-based color converters for white light-emitting diodes (LEDs). The SiNPs with tunable fluorescent color ranging from blue to yellow-green could be achieved through an optimized microwave synthetic method. Fluorescent SiNPs with tunable luminescent color, whose maximum emission wavelengths (λemission) range from 460 to 545 nm. Of particular significance, the SiNPs exhibiting broadband yellow-green emission prepared at pH value of 4 are demonstrated to be suitable for forming the basis of a white spectrum, which are thus further employed as color converter for the construction of white LED. The resultant LED devices exhibit a luminous efficiency (LE) of 13 lm W-1, CIE chromaticity coordinates of (0.3041, 0.3129), CRI of 82, and correlated color temperature (CCT) of 7982 K. Keywords: Fluorescent silicon