掺杂ZnSe纳米颗粒的合成和表征-凝聚态物理专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 Abstract Nanoparticles (quantum dots) are widely used in biomarkers, miniature photoelectric device, photosensitization solar cell, organic chemical detection and so on. This paper mainly studies a greener Se precursor to synthesize doping ZnSe nanoparticles. By changing doping ion and doping concentration to, we study they have an impact on the luminescence properties of ZnSe nanoparticles. Firstly, this paper adopts hot inject successfully synthesis of monodispersity and high quality of ZnSe, Cu:ZnSe, Cu:ZnSe /ZnS nanoparticles. Its size is 4.73nm～6.26nm. And by studying the preparation conditions of nanoparticles, we find when doping concentration is 8%, inject temperature of Se precursor is 240℃, growth temperature is 270℃, growth time is 20min, (like Cu:ZnSe/ZnS (there should be two layers of ZnS)), nanoparticle’s luminescent properties is better. ZnSe ， Cu:ZnSe ， Cu:ZnSe/ZnS nanoparticle’s absorption peak is 380nm. Photoluminescence peak is 436nm and 472nm. QY is 42.6%~63.6%. Secondly, we measured photoluminescence spectrum of Cu:ZnSe/ZnS nanoparticles under the pulsed magnetic field. We proved that the PL Intensity of nanoparticles are mainly caused by quantum size effect; Magnetic field can strengthen radiation between conduction and copper ions’ t2 level; Magnetic field effects on the PL Intensity of nanoparticles which is not drab; You can clearly see the PL Intensity of Cu: ZnSe/ZnS nanoparticles enhanced at low temperature, it will widen the application range of nanoparticles. Finally，we also adopt hot inject successfully synthesis of monodispersity and high quality of Ce:ZnSe，Ce:ZnSe/ZnS，Er:ZnSe，Er:ZnSe/ZnS，Ce:Cu:ZnSe，Ce:Cu:ZnSe/ZnS nanoparticles. Its size is 10nm. Their preparation methods is similar to the preparation method of Cu:ZnSe, Cu:ZnSe /ZnS nanoparticles. QY is about 34.6%. Keywords: Doping ZnSe nanoparticles Photoluminescence Environmental protection Pulsed high magne