超临界二氧化碳协助功能化三维石墨烯的制备及其在超级电容器方面的应用-材料学专业论文.docxVIP

Abst Abstract 万方数据 万方数据 Abstract Graphene, a novel one-atom-thick two-dimensional nanomaterial, has attracted much attention, owing to its outstanding chemical and physical properties. In order to expand the application of graphene-based materials in environment, energy, biological and sensing fields, it is necessary to assemble 2D graphene sheets into 3D architectures. It may furnish graphene materials with higher specific surface areas, stronger mechanically strengths and faster mass and electron transport kinetics because of the combination of 3D porous structure and the outstanding intrinsic properties of graphene. Building three-dimensional graphene-based hybrid nanostructures with anticipated function has become one of the most active research fields. Considering the single-phased nanomaterials always have their intrinsic defects, scientists are inclined to combine unique properties of individual nanostructures and explore their synergistic effect. Considering its low viscosity, high diffusivity, zero surface tension, and plasticization to polymer, SC CO2 has been applied in the fabrication of nanomaterials. In view of the soft matter theory and the great tunabililty of SC CO2, it is anticipated that nanocomposites of tailored structure and controlled assembly of nanoparticles can be achieved with the help of SC CO2. Therefore, the main content of my research subject includes: The architectures of 3D graphene-pyrrole/carbon nanotube/polyaniline (GPCP) nanohybrids can be successfully prepared by dipping the G-Py aerogel into the CNT/PANI nanocomposites solution. The incorporation of CNT/PANI into the porous structures of graphene-based foam could prevent aggregation/restacking of graphene sheets to miantian the foam architectures. Also, the well deposition of PANI nanorods on CNT effectively increases the electrochemical utilization of PANI, and reduces the ion diffusion path in the process of charge-discharge, which result in outstanding electrochemical proper