功能材料图7彩印响应面法优化废旧PET催化醇解工艺.DOCVIP

收稿日期：2018-02-28；DOI：10.13550/j.jxhg基金项目：国家自然基金项目51663014）；甘肃省黏土矿物应用研究重点实验室项目（CMAR-04） 作者及联系人简介：徐惠（1966-），女，教授，博士生导师，电话E-mail：xuhui@lut.cn 功能材料 (图7彩印)响应面法优化废旧PET催化醇解工艺 201802280133 徐惠，熊峰，彭振军，陈泳，刘映含 （兰州理工大学石油化工学院，甘肃 兰州 730050） 摘要：在常压下采用催化剂一步醇解废旧聚酯(PET)工艺制备聚酯多元醇，并采用物理发泡方式用该聚酯多元醇制备了硬质聚氨酯泡沫塑料，达到废旧PET的循环利用。以催化醇解得到聚酯多元醇的羟值、酸值和黏度为指标，筛选催化剂用量、醇解剂用量和醇解时间为主要因素，通过响应面法优化得到催化醇解废旧PET的最佳工艺条件，即质量分数0.3%（占PET的质量，下同）的Sb2O3作为解聚的催化剂、质量分数100%的二甘醇为醇解剂，醇解反应时间为2.5h，通过实验验证表明该条件可靠，实际得到的聚酯多元醇羟值503.9mgKOH/g，酸值2.4mgKOH/g，室温粘度1310mPa·s，以该聚酯多元醇为原料制备硬质聚氨酯泡沫的导热系数为0.02～0.03W/(m·K)，密度为40～50kg/m3，表明通过该方法实现废旧PET的循环利用是可行的，并提高了其循环利用价值。 关键词：废旧聚酯；催化醇解；聚酯多元醇；响应面法； 中图分类号：O633.14 文献标识码：A 文章编号：201802280133 Optimization of Catalytic Alcoholysis Process of Waste PET(Polyethylene Terephthalate) by Response Surface Methodology XU Hui, XIONG Feng, PENG Zhen-jun, CHENYong, LIU Ying-han (College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, China) Abstract: Polyester polyols were prepared by an one-step depolymerization of polyethylene terephthalate (PET) using catalysts under ordinary pressure and then used as raw material to prepare rigid polyurethane foam by physical foaming method. The hydroxyl value, acid value and viscosity of polyester polyols were used as evaluation index to investigate the effects of catalyst dosage, dosage of alcoholysis agent and pyrolysis time on the alcoholysis process of PET by using response surface methodology (RSM). The optimum process conditions were obtained as follows: the mass fraction of catalyst (Sb2O3) was 0.3% (based on the weight of PET, the same below), diethylene glycol (DEG) with a mass fraction of 100% was used as alcoholysis agent, reaction time was 2.5 h. The experimental verification indicated that the conditions by RSM analysis were reliable. The hydroxyl value, acid value and viscosity of the product were 503.9 mg KOH/g, 2.4 mg KOH/g and 1310 mPa·s, respectively.