发泡聚丙烯粘接成型的研究材料物理与化学专业论文.docxVIP

定性的影响。实验表明：乳化剂用量为 20%具有较好的稳定性，剪切搅拌速度 越高，使乳液小分子剪切越小，乳液越稳定。 5. 丙烯酸酯乳液胶粘剂、环氧乳液粘接 EPP1 及 EPP2 成型的研究。考察表 面改性方式、胶粘剂用量及增塑剂用量对 EPP1 粘接性能的影响，及接枝率、固 化剂及环氧乳液用量对 EPP2 粘接性能的影响。结果表明，经铬酸处理及包覆丙 烯酸酯胶 EPP1 都较未处理粘接性能增大，包覆丙烯酸酯胶粘接效果更好，密度、 拉伸强度和断裂伸长率都随着胶量的增加而增加，增塑剂用量为 4%较适宜； EPP2 粘接成型随着 MAH 接枝率的升高，拉伸强度也逐渐增大，随着环氧乳液 用量的增加，拉伸强度逐渐增强；丙烯酸酯乳液粘接 EPP1 性能优异，环氧乳液 粘接 EPP2 性能优异。 关键词：发泡聚丙烯，粘接，表面改性，成型 ABSTRACT As a type of novel foam plastic, expanded polypropylene (EPP) develops very quickly in recent years due to its many outstanding properties like excellent anti-knock and absorbed energy property, high deformation recovery, high thermal resistance, excellent chemical resistance, oil resistivity and thermal insulation and so on, as well as its better environmental friendliness property than other foam materials. At present, EPP productions are mainly manufactured by way of second batch and molding processing, the shortcomings of which include long manufacturing cycle, large investment of equipment, the structure complex of mould, high demanding of design, and maintaining difficulty, as well as tough requirements of process parameters, all of which hinder seriously the wide application of EPP productions in many enterprises, especially minor enterprises. As a result, a simple and easy progressing technology to satisfy the market demanding of EPP production is badly in need of exploiting. Given this situation, in this article a new method that assuming the simple bonding molding processing is put forward to replace the tradition molding technology. The main research contents and conclusions are as follows: The surface of EPP that foaming time is 40 (EPP1 for short ) was modified by means of chromic acid dipping and hypothermia emulsion polymerization, and then characterized by SEM、XRD、TG、FTIR and so on. The results show that the optimal conditions of chromic acid dipping modification to get a rough surface of EPP is: processing temperature 45 ℃ , the dealing time 60 min, chromic acid concentr