反渗透-Fenton氧化法处理高浓度有机磷工业废水-分析化学专业论文.docxVIP

率分别为 87.6%、94.7%，达到了污水处理厂的排放要求。 关键词：季膦盐废水；反渗透；Fenton；四羟甲基硫酸磷；四羟甲基氯化磷；化学 需氧量；磷 Abstract In recent years, reverse osmosis(RO) is widely applied in the field of wastewater treatment. However, it seems that the treatment of waste with tetrakis hydroxymethyl phosphonium salt(THP) are rarely reported. Due to hight content of chemical oxygen demand(COD), biotoxicity and salinity, it can be hardly treated by conventional biochemical technology. In this thesis, RO-Fenton method was firstly adopted for the recovery of THP and qualified wastewater discharge. The main contents included:①the removal of phosphorus in the waste of tetrakis(hydroxymethyl)phosphonium sulfate(THPS) by ion exchange resin;②the application of reverse osmosis in the separation of phosphorus in THP waste;③the degradation of COD in simulated wastewater and RO permeat using Fenton reagent. The results were summarized as follows: ⑴Strong-acid cation exchange resin was selected as the study subject due to higher static adsorption capacity and adsorption rate. Dynamic experiments showed that at room temperature, 9.7 g resin was acceptable for 500 mL THPS waste at flow rate 15 mL/min and it was regenerated by 250 mL 1 mol/L HCl at 5 mL/min. Under studied conditons, dynamic adsorption capacity of THPS was up to 10.73 mg/g, the desorption efficiency of resin came to 89.73% and long time use of resin had a negative effect on the regeneration process. Furthermore, the effluent were not in line with emission standards, in which average total phosphorus(TP), HCHO and COD were 28.43 mg/L, 2481.5 mg/L and 992.3 mg/L, respectively. ⑵The performance of RO system to reuse and remove THP from the waste was studied. With a feed pressure of 70 bar and a flow of 3 m3/h, the average rejections of THPS and tetrakis(hydroxymethyl)phosphonium chloride(THPC) were 98.7% and 97.6%, which resulted in total phosphorus in the permeat lower than 10 mg/L for both THPS and THPC waste. As for RO concentrate where THPS a