超声作用下Ormosil的制备及在微滴乳液聚合中原位纳米复合-材料化学工程专业论文.docxVIP

obtained. The PDMS-modified silica sol was dispersed in the mixed monomers of methylmethacrylate(MMA) and butylmethacrylate(BA). Then miniemulsion polymerizations of the acrylate monomers containing PDMS- modified silica sol were carried out, with PDMS as hydrophobe to inhibit the Ostwald ripening of the monomer droplets and neutralized DBSA as emulsifier, both preexisted in the PDMS- modified silica sol. The composite latex was obtained via miniemulsion polymerization. FTIR, TGA, TEM, Malvern Nanosizer and water contact angle tests were utilized to characterize the modified silica and the composite latex. The results show that silica is grafted and encapsulated by PDMS and KH560 with chemical bonds and is well dispersed in monomers, and the generated PDMS improves the hydrophobicity of the film of nanocomposite latex. The average size of nanocomposite particles with a (multi)core-shell structures is 98nm when the silica mass ratio is 3% of the monomers. KEY WORDS：Silica;Miniemulsion polymerization; Nanocomposite; Ultrasonic. 目 录 HYPERLINK \l _bookmark0 目 录 HYPERLINK \l _bookmark1 前 言1 HYPERLINK \l _bookmark2 第一章 文献综述3 HYPERLINK \l _bookmark3 1.1 有机无机纳米复合材料3 HYPERLINK \l _bookmark4 1.1.1 有机无机纳米复合材料的构成形式3 HYPERLINK \l _bookmark5 1.1.2 有机无机纳米复合的制备3 HYPERLINK \l _bookmark6 1.2 纳米SiO2 5 HYPERLINK \l _bookmark7 1.2.1 纳米SiO2 的特性 6 HYPERLINK \l _bookmark8 1.2.2 硅溶胶的制备方法7 HYPERLINK \l _bookmark9 1.2.3 纳米SiO2 的表面改性 7 HYPERLINK \l _bookmark10 1.2.4 纳米SiO2 在聚合物基体中的分散 10 HYPERLINK \l _bookmark11 1.2.5 纳米SiO2 对复合材料力学性能的影响 10 HYPERLINK \l _bookmark12 1.3 超声11 HYPERLINK \l _bookmark13 1.3.1 超声的基本原理及特点11 HYPERLINK \l _bookmark14 1.3.2 声化学研究进展12 HYPERLINK \l _bookmark15 1.4 微滴乳液聚合15 HYPERLINK \l _bookmark16 1.4.1 单体微滴乳液的制备15 HYPERLINK \l _bookmark17 1.4.2 微滴乳液聚合在制备有机无机纳米复合体系上的应用18 HYPERLINK \l _bookmark18 1.5 本文的研究目标与内容19 HYPERLINK \l _bookmark19 第二章 丙烯酸酯/纳米SiO2 的微滴乳液聚合与杂化 20 HYPERLINK \l _bookmark20 2.1 实验部分20 HYPERLINK \l _bookmark21 2.1.1 实