负载型过渡金属氧化物催化剂催化氧化NO的实验研究-热能工程专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - Abstract Over 90% of NOx in flue gas of coal-fired power plant is NO that is difficult to be absorbed by calcium-based absorbents. The simultaneous desulfurization and denitrification technology based on calcium-based absorbents has been significant as a research direction of combined removal, which has important value. To enhance the denitration efficiency by calcium-based absorbents and achieve the aim of simultaneous desulfurization and denitrification technology, NO must to be turned into NO2 first. The research contents of this paper is to find effective catalyst, study the best preparation condition of it and test the influence of the flue gas composition on catalytic oxidation of NO, to realize the simultaneous desulfurization and denitrification technology. Investigations of NO catalytic oxidation over supported metal oxides were conducted by fixed-bed. The influence of temperature on catalytic oxidation of NO was tested and the results show that the catalytic activity of Mn/Zeolite, Co/Zeolite, Cu/Zeolite, Fe/Zeolite is rather low when the temperature is lower than 250℃ while the relative order of the catalytic activity are MnOxCoOxCuOxFeOx when the temperature is between 250℃ and 350℃. Tests were conducted to analyze the influence of promoter and additive on catalytic oxidation of NO by MnOx-based catalyst. The results show that the activity is higher by adding Co3O4, CeO2 and CuO, while the activity is lower by adding Fe2O3. The conversion on the surface of Mn-Ce/Zeolite is 12% higher than Mn/Zeolite when the temperature is 300℃. Tests were conducted to research the influence of carrier on catalytic activity. The results show that it has great influence on activity of catalytic. The activity and stability of MnOx/RHA is preferably, and the RHA is so cheap, thus RHA is better choice of new type catalysts carrier. The influence of catalysts preparation conditions was studied. The results show that the best prepara