改性皮革胶原纤维对水体中重金属离子的富集特性研究-环境科学专业论文.docx

本文研究了改性皮革胶原纤维对水体中几种重金属离子的富集条件、富 集机理等富集特性。 在 pH=6.0 的情况下，改性皮革胶原纤维能很好地富集 这几种重金属离子; 1.02.伽lOl!L的 HN03 能完全洗脱被富集的重金属离 +子。同时研究了温度和时间对改性皮革胶原纤维富集 Cu2 + 的影响，以及改 性皮革胶原纤维对这几种重金属离子的富集容量，以及水体中常见无机粒子 Mg2+、K+，NH3 对改性皮革胶原纤维富集重金属离子的影响， 由试验得知，改性皮革胶原纤维是一种良好的固体络合剂。可以定量富 集水体中多种微量重金属，它具有富集倍数大，吸附效率高，吸附速度快， 解脱性能好，制备简单，操作方便，可多次重复使用、易于推广等优点。是 继琉基棉、黄原酶棉、泡沫塑料、壳聚糖纤维素之后的又一大自然界储量丰 富、且不易带来化学影响的环保型富集材料。对于改性皮革胶原纤维作为吸 附材料的研究还需进行更加深入的开展，并使其形成产品加以推广和应用。 关键词:改性皮革胶原纤维 络合 重金属离子 富集特性 Abstract Metals which specific gravity larger tban 5.0 or equal to 5.0 are heavy metals. Heavy metals ωnt de∞mposed by animalcule. On the con位町， org扭ism can enrich them and trasfer them to mental-organic compound wich have more toxicity. Because of 也就， heavy metals 缸e one of latent contamination. Along W?th the development of industrial of platinglcurry/antisepsis and dye matte乓 more and more waste water containing heavy metal ion was let out. As result，the health of human being and the security of en由onment were in 也nger. Since 1950s ，bone ache disease appeared in Japanωa wicked result of Cadmium pollution，pωple paid more attention to 也e pollution of heavy metals. Scholars made abroad and in-depth research on the chemical characters of heavy metal ion in water. In all those studies ，analysis of heavy metal work as basic research. Due to low ωntent of heavy metal ion in water; 姐d ∞Implex ∞mposingof 也ew创er，every group have influence on different chec挝ng method. Mass of instrument analysis，such as Emission spectrometry 细.d Pol缸ography，has not enough sensitivity . Even if it ∞uld check those low consistence element，basic element did infection on exactitude and precision of the checking method. Therefore enriching the trace heavy metal ion and separating it from basic element are necess缸予 Leather glue fibril ∞nstitute W?th tissue fibrin， and it occupies 95-..98% 坦 ∞rium fibrin. Glue fibril have a la唱 amount of function groups such as -CONH-/-OH/-COOH/-NH2. and have speci挝 solid reticu