高分子引导下无机材料形貌调控-材料学专业论文.docxVIP

AbstractThe Abstract The controlled synthesis of inorganic or inorganic／organic hybrid materials with specific shape or highly ordered hierarchical architecture is a key challenge in current materials synthesis and device fabrication．Recently,bio-inspired synthesis strategy has been explored as a promising approach for the morphological control and crystal tectonics．The main contents of our work are summarized as follows： Firstly,PSMA is selected as a crystal modifier,taking advantage ofthe cooperative effects of related experimental parameters such as the concentration of PSMA，pH value of solution，and molar ratio of cation to anion僻)，to control the morphology of inorganic materials，including BaSO,，SrS04，and BaCr04，giving rise to the emergence of a variety of interesting morphologies A series of control experiments have been carried out to understand the morphological change with the variation of experimental conditions．The results indicate that the effect of all those parameters 0n the morphologies and crystallization of inorganic mineral can be attributed to their influence on the interaction between the carboxylic acid groups ofPSMA and the crystal planes of the surface of inorganic mineral In addition，a preliminary understanding for the formation mechanism of certain wonderful morphology has been proposed on the basis of the experimental results SecondlN monodispersed quasi—octahedral PbW04 crystals have been fabricated via a simple PbW04 precipitation reaction in the mixed synthetic system of PVP and CTAB．The cooperative effect of PVP and CTAB is found to be responsible for the morphological transformation process from PbW04 pagodas to the unique PbW04 quasi-octahedrons．The photolumjnescence property for the unique PbW04 quasi—octahedrons is observed to be significantly different from that for the PbW04 pagodas． Finally,Single crystalline vanadium oxide nanobelts have been synthesized on a large scale by hydrothermal treatment ofNH4VOs in the presence ofthe pol