高分子光限幅材料的分子设计及合成-高分子化学与物理专业论文.docxVIP

妒46G436摘 妒46G436 摘 要 本文蔽据K．C．Rustagi和P N．Prasad非线性光学理论，设计了将具有大的 共轭程度的偶氮苯非线性基团直接接枝于共轭的聚炔类高分子，制备新颖的光 学聚炔类材料。主要征作内容如下： 1．本论文综述了国内外各类光限幅材料研究的历史和最新进展，详细探讨了光 限幅材料的各种限幅机理及其应用。 2．设计了两个系列共六个目标单炔化合物，对各种单炔合成路线的进行了讨 论，选择了较为合适的合成路线，合成了十四个产物分子和中间体，其中九 个未见报导。 3．用[Rh(NBD)C1]：作聚合催化剂，成功聚合了六个目标单炔中的三个。详细研 究了聚合条件(时间、溶剂、催化剂、共催化剂)对聚合的影响。(将单炔化 ＼ 合物与苯乙炔共聚，得到可溶性的单体和苯乙炔共聚物。将单体，苯乙炔和 、 C。共聚，得到了含c。的聚炔类高聚物，并发现了C。。的共催化作用。火 4．对六个单炔化合物和部分聚合物进行了光限幅效应研究，发现它们对40 ps 脉宽，1064 nm的激光呈现出较好的光限幅性能。并初步探讨了光限幅机理。 关键词：聚炔i非线性光学i光限幅： 奠徽大学坝l‘论文Abstract 奠徽大学坝l‘论文 Abstract Based on K．C．Rustagi’s and P．N．Prasad’s nonlinear optical theory，some kind of new conjugated polyacetylenes’optical material were designed and synthesized．Their optical limiting properties were measured and the relationship between molecular structure and optical properties were investigated．The main content of this work consists ofthe following points． 1，The history and recert development of the research on optical limiting materials their application，the principle and mechanism of optical limiting were systematically summarized． 2．Based on the nonlinear optical theory,Six objective monomer molecules were designed．Their synthetic routes were selected on the basis of discussion of various synthetic methods ofacetylenic compounds． 3．Three of six objective molecules were successfully polymerized，using [Rh(nbd)C1]2 as catalyst and their copolymers with C60 were prepared．Influence of differert polymeric conditions，such as time，solvent，catalyst，cocatalyst，on polymerization were studied in detail．Simultaneously,we found that C60 plays double functions鹊comonomer and as cocatalyst．To improve the solubility of these homopolymers，the objective monomers were copolymerized with phenylacetylene to give soluble polymers． 4．The optical limiting effects of all six acetylenic monomers and some polymers were measured and it was found that they possess good limiting effects under 40 ps pulse laser at the wavelength of 1064 am．Their limiting mechanism were also investi