高密度聚乙烯热塑性聚氨酯的共混及其γ辐照效应-材料学专业论文.docxVIP

摘 摘 要 (4)．结晶形态研究表明，增容剂的加入会使HDPE的结晶不同程度的细化。增容 剂含量越高，HDPE的结晶细化程度越大。 (5)．SEM研究表明，经T一辐照或／和增容剂的加入，增强了HDPF_YFPU的相界面 粘结作用力，改善了HDPE与TPU的相容性。 (6)．经丫．辐照或／和向共混体系中加入增容剂，HDPE／rPU体系的熔体流动速率 有所降低，且随着辐照剂量和增容剂含量的增加而降低。 (7)．所制备的HDPEtTPU、HDPE／增容剂tTPU共混体系的熔体均为假塑性流体， 其表观粘度分别随温度的升高和剪切速率的增大而降低， HDPP／EVA-g-MAH／TPU熔体的表观粘度随共混物中mEVA用量的增加变化不 大；加入一定量的mEVA，可以降低共混体系粘度对温度的敏感程度。 关键词： 高密度聚乙烯热塑性聚氨酯·T．辐照增容剂性能形态 II AbstractThe Abstract The HDPE／TPUs of Blending and Their Effect of y—Radiation ABSTRACT In this work，the blends with different ratios of high-desity polyethylene ／thermoplastic polyurethane(HDPE／TPU)were prepared through melt mixing by using a twin-screw extruder,with EVA-g-MAil(mEVA)、POE-g-MAH(mPOE)， PNl and PN2(which WgIe made by our own laboratory)as eompatibilizers． y-Radiation treatment of different doses(D_25kGy)was applied to the blends for the first time．The effect of theT-radiation and compatibilizer on their mechanical properties、thermo properties、rheological behavior、structure and morphology were systematically investigated． HDPE and TPU are immiscible,The mechanical property of simply blended HDPE／TPU could be improved through thcT-radiation at modest radiation dose㈣ and the introduction ofthe compatibilizer,and their strength、rigidity and toughness of the blends were improved greatly．In the HDPE／TPU(90：10)blends EVA．g-MAH performanced better in improving the notched Izod impact strength than other compatibilizers used in the experiment．The notched Izod impact strength of the HDPE／mEVA／TPU was gradually enhaanced with the increase of compatibilizer content in the mEVA range from 2 to 10 phr．While PN2 was better than other compatibilizers in improving the tensile strength and the modulus．In the TPU／HDPE (90：10)blends the ability in improving the machanical properties is ranked in a decreasing order as POE·g-MAHPNlEVA-g—MAHⅫ-radiation．In the rang of 2～1 0phr,it was enough to improve the compatibility of the blend when POE—g-MAH was introduced about 2phr． It was showed that the the